Fine tuning the electronic properties of [M(bpy)3]2+ complexes by chemical pressure (M = Fe2+, Ru2+, Co2+, bpy = 2,2'-bipyridine)
A. Hauser, N. Amstutz, S. Delahaye, S. Schenker, A. Sadki, R. Sieber and M. Zerara
in "Structure and Bonding"
(ed. Th. Schönherr), Springer, Berlin,
106 (2003), p81
The physical and photophysical properties of three classic transition metal complexes, namely [Fe(bpy)3]2+, [Ru(bpy)3]2+, and [Co(bpy)3]2+, can be tuned by doping them into a variety of inert crystalline host lattices. The underlying guest-host interactions are discussed in terms of a chemical pressure.
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