- Hybrids of Cationic Helicene and N-Heterocyclic Carbene as Ligands for Complexes Exhibiting (Chir)Optical Properties in the Far Red Spectral Window
Robert Tarrieu, Irene Hernandez Delgado, Francesco Zinna, Vincent Dorcet, Sophie Colombel-Rouen, Christophe Crévisy, Olivier Baslé, Johann Bosson, Jérôme Lacour
Chem. Commun. 2021, 57, 3793-3796
Synthesis, electronic and structural properties of a chiral NHC bearing a N-bonded cationic helicene moiety are reported. This ligand is used to construct AuI, AuIII and RhI complexes exhibiting far-red (chir)optical properties regardless of the metal.
open archive unige:150998