63. Vibrational and Electronic Circular Dichroism of Δ-TRISPHAT [Tris(tetrachlorobenzenediolato)phosphate(V)] Anion
    Delphine Bas, Thomas Bürgi, Jérôme Lacour, Jérôme Vachon, Jacques Weber
    Chirality 2005, 17, S143-S148

Herein is reported an experimental and theoretical study of the circular dichroism properties of TRISPHAT (1) anion. ECD analysis of the [tetramethylammonium][Δ‐1] salt confirms the absolute configuration assignment obtained through X‐ray crystallographic analysis of the parent cinchonidium salt. The structure, infrared, and vibrational circular dichroism (VCD) spectra derived from density functional theory (DFT) calculations are compared with experimental data.

DOI : 10.1002/chir.20131 

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