- Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
Viñas-Lóbez, J.; Levitre, G.; de Aguirre, A.; Besnard, C.; Poblador-Bahamonde, A. I.; Lacour, J.
ACS Org. Inorg. Au 2021, 1, 11-17
Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CH3CN)3][BArF] catalysis. The dual reactivity of these 2-vinyloxymalonates can be used to expand the classical range of cyclizations derived from carbonyl ylide intermediates.
open archive unige:155213