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Publication 154
- “Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling”
X. Urbaneja, A. Mercier, C. Besnard, E.P. Kündig,
Chem. Commun. 2011, 47, 3739-3741.
Access to planar chiral complexes has been sought by catalytic desymmetrisation of a prochiral complex via asymmetric Suzuki-Miyaura cross-coupling. High selectivities of up to 98% ee were achieved using a bulky chiral palladium catalyst.
DOI : 10.1039/C1CC10347D
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