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Publication 114
- Asymmetric syntheses of α-amino acids from α-halogenated 10-sulfonamido-isobornyl esters.
Oppolzer, W.; Pedrosa, R.; Moretti, R.
Tetrahedron Lett. 1986, 27, 831-834
Treatment of chiral α-haloesters 2 with NaN3 gave azidoesters 3 which on successive transesterification and hydrogenolysis furnished α-amino acids 5 and 9 in high e.e.