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Publication 90
- Asymmetric diels-alder reaction of a chiral allenic ester : enantioselective synthesis of (–)-β-santalene
Oppolzer, W.; Chapuis, C.
Tetrahedron Lett. 1983, 24, 4665-4668
The Lewis-acid promoted Diels-Alder reaction of the allenic ester 10 provides the adduct 11 with excellent π-facial selection leading to an efficient enantioselective synthesis of (−)-β-santalene and to the recovery of the chiral control element 7.