87. TRISPHAT-N: A Chiral Hexacoordinated Phosphate Anion with Unique Asymmetric Coordinating Properties
    Samuel Constant, Richard Frantz, Jessica Müller, Gérald Bernardinelli, Jérôme Lacour
    Organometallics 2007, 26, 2141-2143

A simple and efficient chiral anionic N-ligand:  the introduction of a Lewis basic nitrogen onto the TRISPHAT skeleton allows the direct and efficient stereocontrol of tropos chiral ligands bound to metal complexes or of stereogenic metal centers (dr up to 96:4).

DOI : 10.1021/om070074k 

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