- Sisson, A. L.; Sakai, N.; Banerji, N.; Fürstenberg, A.; Vauthey, E.; Matile, S. “Zipper Assembly of Vectorial Rigid-Rod π-Stack Architectures with Red and Blue Naphthalenediimides: Toward Supramolecular Cascade n/p-Heterojunctions” Angew. Chem. Int. Ed. 2008, 47, 3727-3729
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Zipped up: Supramolecular 3D organization on gold with interdigitating intra- and interlayer recognition motifs (see picure, black p-oligophenyl rods; red, blue naphthalenediimide (NDI) stacks) is designed to access supramolecular cascade n/p-heterojunctions or the adaptable directionality needed to control fill factors in current–voltage curves.