8. Solid-Phase Synthesis of Oligosaccharides: Construction of a Dodecasaccharide
   K. C. Nicolaou, N. Watanabe, J. Li, J. Pastor, N. Winssinger
   Angew. Chem. Int. Ed. 1998, 37, 1559-1561

Complicated oligosaccharides such as dodecasaccharide 1 can be constructed by a new solid-phase strategy. The attachment to the polymeric support (gray sphere) is through a photolabile linker (structure I), and thioglycosides serve as carbohydrate donors. Bn=benzyl, Bz=benzoyl.

DOI : 10.1002/(SICI)1521-3773(19980619)37:11<1559::AID-ANIE1559>3.0.CO;2-E 

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