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A.-S. Chauvin, G. Bernardinelli, A. Alexakis,
“Determination of the absolute configuration of chiral cyclic alcohols using diamine derivatizing agents by 31P NMR spectroscopy”
Tetrahedron: Asymmetry 2006, 17, 2203-2209.
The absolute configuration and enantiomeric excess of chiral cyclic alcohols can be predicted from the 31P NMR spectra of the two diastereoisomers obtained with organophosphorus diamino-derivatizing agents (CDAs) and the chiral secondary alcohol, according to a simplified model taking into account the spatial location of the substituents of the chiral alcohol center and the 31P NMR signals of the two diastereoisomers.
DOI : 10.1016/j.tetasy.2006.07.042
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