Département de chimie organique Département de chimie organique

Publications


  1. R. Lagoutte, C. Besnard, A. Alexakis,
    “Direct Organocatalysed Double Michael Addition of α-Angelica Lactone to Enones”
    Eur. J. Org. Chem. 2016, 4372-4381.
  1. S. Goncalves-Contal, L. Gremaud, L. Palais, L. Babel, A. Alexakis,
    “Copper-Catalyzed Enantioselective Conjugate Addition to α,β-Unsaturated Aldehydes with Various Organometallic Reagents”
    Synthesis 2016, 48, 3301-3308.
  1. P. Cottet, C. Bleschke, M.G. Capdevila, M. Tissot, A. Alexakis,
    “Catalytic Enantioselective Total Synthesis of Riccardiphenol B”
    Adv. Synth. Catal. 2016, 358, 417-425.
  1. J. Praz, J. Graff, L. Egger, L. Guénée, S. Wagschal, E.P. Kündig, A. Alexakis,
    “Asymmetric bromine–lithium exchange: on the importance of both the diamine ligand and the organolithium reagent”
    Chem. Commun. 2015, 51, 16912-16915.
  1. D. Grassi, A. Alexakis,
    “Improvements and Applications of the Transition Metal-Free Asymmetric Allylic Alkylation using Grignard Reagents and Magnesium Alanates”
    Adv. Synth. Catal. 2015, 357, 3171-3186.
  1. J. Graff, E. Łastawiecka, L. Guénée, F. Leroux, A. Alexakis,
    “Asymmetric Bromine-Lithium Exchange: Application toward the Synthesis of New Biaryl-Diphosphine Ligands”
    Adv. Synth. Catal. 2015, 357, 2833-2839.
  1. N. Germain, A. Alexakis,
    “Formation of Contiguous Quaternary and Tertiary Stereocenters by Sequential Asymmetric Conjugate Addition of Grignard Reagents to 2-Substituted Enones and Mg-Enolate Trapping”
    Chem. Eur. J. 2015, 21, 8597-8606.
  1. F. Romanov-Michailidis, M. Romanova-Michaelides, M. Pupier, A. Alexakis,
    “Enantioselective Halogenative Semi-Pinacol Rearrangement: Extension of Substrate Scope and Mechanistic Investigations”
    Chem. Eur. J. 2015, 21, 5561-5583.
  1. P. Garcia, N. Germain, S. Woodward, A. Alexakis,
    “Copper-Catalyzed Asymmetric Conjugate Addition to α-Alkylidene Cycloalkanones”
    Synlett 2015, 26, 901-906.
  1. A. Lefranc, L. Guénée, S. Goncalves-Contal, A. Alexakis,
    “Direct Organocatalytic Construction of Bicyclo[3.2.1]octanes by Domino Michael/Aldol Reaction with β,γ-Unsaturated 1,2-Keto Amides”
    Synlett 2014, 25, 2947-2952.
  1. H. Li, D. Grassi, L. Guénée, T. Bürgi, A. Alexakis,
    “Copper-Catalyzed Propargylic Substitution of Dichloro Substrates: Enantioselective Synthesis of Trisubstituted Allenes and Formation of Propargylic Quaternary Stereogenic Centers”
    Chem. Eur. J. 2014, 20, 16694-16706.
  1. A. Lefranc, L. Gremaud, A. Alexakis,
    “Construction of Bicyclo[3.2.1]octanes with Four Stereogenic Centers by Organocatalytic Domino Michael/Aldol Reaction”
    Org. Lett. 2014, 16, 5242-5245.
  1. F. Romanov-Michailidis, M. Pupier, C. Besnard, T. Bürgi, A. Alexakis,
    “Enantioselective Catalytic Fluorinative Aza-semipinacol Rearrangement”
    Org. Lett. 2014, 16, 4988-4991.
  1. A. Alexakis, F. Romanov-Michailidis, M. Pupier, L. Guénée,
    “Enantioselective halogenative semi-pinacol rearrangement: a stereodivergent reaction on a racemic mixture”
    Chem. Commun. 2014, 50, 13461-13464.
  1. D. Grassi, A. Alexakis,
    “Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution”
    Chem. Sci. 2014, 5, 3803-3807.
  1. N. Germain, D. Schlaefli, M. Chellat, S. Rosset, A. Alexakis,
    “Domino Asymmetric Conjugate Addition-Conjugate Addition”
    Org. Lett. 2014, 16, 2006-2009.
  1. M. Tissot, H. Li, A. Alexakis,
    “Copper-Catalyzed Asymmetric Conjugate Addition and Allylic Substitution of Organometallic Reagents to Extended Multiple-Bond Systems”
    in Copper-Catalyzed Asymmetric Synthesis; A. Alexakis, N. Krause, S. Woodward (Eds.)Wiley-VCH, 2014; Chapter 3; p. 69-85.
  1. A. Alexakis, N. Krause, S. Woodward,
    “Copper-Catalyzed Asymmetric Conjugate Addition”
    in Copper-Catalyzed Asymmetric Synthesis; A. Alexakis, N. Krause, S. Woodward (Eds.)Wiley-VCH, 2014; Chapter 2; p. 33-69.

  1. A. Alexakis, N. Krause, S. Woodward (Eds.)
    “Copper-Catalyzed Asymmetric Synthesis”
    Wiley-VCH, 2014, 472 pp.
  1. D. Willcox, S. Woodward, A. Alexakis,
    “Enantioselective 1,4-additions of ClMeAl(CH=CHR) (R = alkyl, alkenyl, Ph) to cyclohexenones”
    Chem. Commun. 2014, 50, 1655-1657.
  1. N. Germain, L. Guénée, M. Mauduit, A. Alexakis,
    “Asymmetric Conjugate Addition to α-Substituted Enones/Enolate Trapping”
    Org. Lett. 2014, 16, 118-121.
  1. A. Quintard, A. Alexakis,
    “Organocatalytic conjugate addition in stereoselective synthesis”
    in Stereoselective Synthesis of Drugs and Natural Products; V. Andrushko, N. Andrushko (Eds.)Wiley, 2013; Chapter 11; p. 319-346.
  1. D. Grassi, A. Alexakis,
    “Copper-Free Asymmetric Allylic Alkylation of Trisubstituted Cyclic Allyl Bromides Using Grignard Reagents”
    Angew. Chem. Int. Ed. 2013, 52, 13642-13646.
  1. S. Goncalves-Contal, L. Gremaud, A. Alexakis,
    “Enantioselective Copper-Catalyzed Conjugate Addition of Trimethylaluminium to β,γ-Unsaturated α-Ketoamides: Efficient Access to γ-Methyl-Substituted Carbonyl Compounds”
    Angew. Chem. Int. Ed. 2013, 52, 12701-12704.
  1. F. Romanov-Michailidis, L. Guénée, A. Alexakis,
    “Enantioselective Organocatalytic Iodination-Initiated Wagner-Meerwein Rearrangement”
    Org. Lett. 2013, 15, 5890-5893.
  1. D. Müller, A. Alexakis,
    “Formation of Quaternary Stereogenic Centers by Copper-Catalyzed Asymmetric Conjugate Addition Reactions of Alkenylaluminums to Trisubstituted Enones”
    Chem. Eur. J. 2013, 19, 15226-15239.
  1. F. Giacomina, A. Alexakis,
    “Construction of Enantioenriched Cyclic Compounds by Asymmetric Allylic Alkylation and Ring-Closing Metathesis”
    Eur. J. Org. Chem. 2013, 6710-6721.
  1. M. Magrez-Chiquet, M.S.T. Morin, J. Wencel-Delord, S. Drissi Amraoui, O. Baslé, A. Alexakis, C. Crévisy, M. Mauduit,
    “Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition”
    Chem. Eur. J. 2013, 19, 13663-13667.
  1. D. Müller, L. Guénée, A. Alexakis,
    “Practical Synthesis of SimplePhos Ligands: Further Development of Alkyl-Substituted Phosphanamines”
    Eur. J. Org. Chem. 2013, 6335-6343.
  1. J. Graff, T. Debande, J. Praz, L. Guénée, A. Alexakis,
    “Asymmetric Bromine–Lithium Exchange: Application toward the Synthesis of Natural Product”
    Org. Lett. 2013, 15, 4270-4273.
  1. F. Romanov-Michailidis, L. Guénée, A. Alexakis,
    “Enantioselective Organocatalytic Fluorination-Induced Wagner-Meerwein Rearrangement”
    Angew. Chem. Int. Ed. 2013, 52, 9266-9270.
  1. M. Tissot, A. Alexakis,
    “Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins”
    Chem. Eur. J. 2013, 19, 11352-11363.
  1. B. Pezzati, M.F. Chellat, J.J. Murphy, C. Besnard, G. Reginato, J.C. Stephens, A. Alexakis,
    “Organocatalytic Asymmetric Annulation of 1,3-Bis(alkoxycarbonyl)buta-1,3-dienes and Aldehydes”
    Org. Lett. 2013, 15, 2950-2953.
  1. C. Bleschke, M. Tissot, D. Müller, A. Alexakis,
    “Direct Trapping of Sterically Encumbered Aluminum Enolates”
    Org. Lett. 2013, 15, 2152-2155.
  1. A. Lefranc, L. Guénée, A. Alexakis,
    “Highly Diastereo- and Enantioselective Organocatalytic Domino Michael/Aldol Reaction of Acyclic 3-Halogeno-1,2-Diones to α,β-Unsaturated Aldehydes”
    Org. Lett. 2013, 15, 2172-2175.
  1. D. Müller, A. Alexakis,
    “Creation of Highly Congested Quaternary Centers via Cu-catalyzed Conjugate Addition of Alkenyl Alanates to β-Substituted Cyclic Enones”
    Org. Lett. 2013, 15, 1594-1597.
  1. P. Cottet, D. Müller, A. Alexakis,
    “Copper-Catalyzed Asymmetric Conjugate Addition of Alkenyl- and Alkylalanes to α,β-Unsaturated Lactams”
    Org. Lett. 2013, 15, 828-831.
  1. D. Grassi, C. Dolka, O. Jackowski, A. Alexakis,
    “Copper-Free Asymmetric Allylic Alkylation with a Grignard Reagent: Design of the Ligand and Mechanistic Studies”
    Chem. Eur. J. 2013, 19, 1466-1475.
  1. H. Li, D. Müller, L. Guénée, A. Alexakis,
    “Copper-Catalyzed Enantioselective Synthesis of Axially Chiral Allenes”
    Org. Lett. 2012, 14, 5880-5883.
  1. D. Muller, A. Alexakis,
    “Rhodium and Copper-catalyzed asymmetric conjugate addition of alkenyl nucleophiles”
    Chem. Commun. 2012, 48, 12037-12049.
  1. D. Grassi, H. Li, A. Alexakis,
    “Formation of chiral fluoroalkyl products through copper-free enantioselective allylic alkylation catalyzed by an NHC ligand”
    Chem. Commun. 2012, 48, 11404-11406.
  1. F. Romanov-Michailidis, C. Besnard, A. Alexakis,
    “N-Heterocyclic Carbene-Catalyzed Annulation of α-Cyano-1,4-diketones with Ynals”
    Org. Lett. 2012, 14, 4906-4909.
  1. N. Germain, M. Magrez, S. Kehrli, M. Mauduit, A. Alexakis,
    “Chiral NHC Ligands for the Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents”
    Eur. J. Org. Chem. 2012, 5301-5306.
  1. M. Magrez, J. Wencel-Delord, A. Alexakis, C. Crévisy, M. Mauduit,
    “Significant Asymmetric Amplification in Enantioselective Cu/DiPPAM-catalyzed 1,6- and 1,4-Conjugate Additions of Diethylzinc to (Di)enones”
    Org. Lett. 2012, 14, 3576-3579.
  1. M. Tissot, D. Poggiali, H. Hénon, D. Müller, L. Guénée, M. Mauduit, A. Alexakis,
    “Formation of Quaternary Stereogenic Centers by NHC–Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Polyconjugated Cyclic Enones”
    Chem. Eur. J. 2012, 18, 8731-8747.
  1. J. Praz, L. Guénée, S. Aziz, A. Berkessel, A. Alexakis,
    “Evaluation of the Chiral DIANANE Backbone as Ligand for Organolithium Reagents”
    Adv. Synth. Catal. 2012, 354, 1780-1790.
  1. L. Gremaud, L. Palais, A. Alexakis,
    “Copper-catalyzed Asymmetric Conjugate Addition to Challenging Michael Acceptors and Synthesis of Relevant Target Molecules”
    CHIMIA 2012, 66, 196-200.
  1. D. Müller, A. Alexakis,
    “Copper-Catalyzed Asymmetric 1,4-Addition of Alkenyl Alanes to N-Substituted-2-3-dehydro-4-piperidones”
    Org. Lett. 2012, 14, 1842-1845.
  1. D. Grassi, A. Alexakis,
    “Copper-Free Asymmetric Allylic Alkylation Using Grignard Reagents on Bifunctional Allylic Bromides”
    Org. Lett. 2012, 14, 1568-1571.
  1. M. Magre, J. Mazuela, M. Diéguez, O. Pàmies, A. Alexakis,
    “Furanoside phosphite–phosphoroamidite and diphosphoroamidite ligands applied to asymmetric Cu-catalyzed allylic substitution reactions”
    Tetrahedron: Asymmetry 2012, 23, 67-71.
  1. J.-B. Langlois, D. Emery, J. Mareda, A. Alexakis,
    “Mechanistic identification and improvement of a direct enantioconvergent transformation in copper-catalyzed asymmetric allylic alkylation”
    Chem. Sci. 2012, 3, 1062-1069.
  1. H. Li, A. Alexakis,
    “Enyne Chlorides: Substrates for Copper-Catalyzed Asymmetric Allylic Alkylation”
    Angew. Chem. Int. Ed. 2012, 51, 1055-1058.
  1. L. Gremaud, A. Alexakis,
    “Enantioselective Copper-Catalyzed Conjugate Addition of Trimethylaluminium to β,γ-Unsaturated α-Ketoesters”
    Angew. Chem. Int. Ed. 2012, 51, 794-797.
  1. J.-B. Langlois, A. Alexakis,
    “Copper-catalyzed Enantioselective Allylic Substitution”
    in Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis; U. Kazmaier (Ed.)Topics in Organometallic Chemistry, Vol. 38; Springer: Berlin / Heidelberg, 2012; p. 235-268.
  1. A. Quintard, J.-B. Langlois, D. Emery, J. Mareda, L. Guénée, A. Alexakis,
    “Conformationally Stabilized Catalysts by Fluorine Insertion: Tool for Enantioselectivity Improvement”
    Chem. Eur. J. 2011, 17, 13433-13437.
  1. D. Müller, M. Tissot, A. Alexakis,
    “New Experimental Conditions for Tandem hydroalumination/Cu-Catalyzed Asymmetric Conjugate Additions to β-Substituted Cyclic Enones”
    Org. Lett. 2011, 13, 3040-3043.
  1. A. Quintard, A. Alexakis,
    “Highly enantioselective organocascade intermolecular iminium/enamine Michael addition on enals”
    Chem. Commun. 2011, 47, 7212-7214.
  1. J.J. Murphy, A. Quintard, P. McArdle, A. Alexakis, J.C. Stephens,
    “Asymmetric Organocatalytic 1,6-Conjugate Addition of Aldehydes to Dienic Sulfones”
    Angew. Chem. Int. Ed. 2011, 50, 5095-5098.
  1. M. Tissot, A. Pérez Hernández, D. Müller, M. Mauduit, A. Alexakis,
    “Highly Enantioselective and Regioselective Copper-Catalyzed 1,4 Addition of Grignard Reagents to Cyclic Enynones”
    Org. Lett. 2011, 13, 1524-1527.
  1. A. Quintard, A. Lefranc, A. Alexakis,
    “Highly Enantioselective Direct Vinylogous Michael Addition of γ-Butenolide to Enals”
    Org. Lett. 2011, 13, 1540-1543.
  1. A. Quintard, A. Alexakis, C. Mazet,
    “Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis”
    Angew. Chem. Int. Ed. 2011, 50, 2354-2358.
  1. J.-B. Langlois, A. Alexakis,
    “Identification of a Valuable Kinetic Process in Copper-Catalyzed Asymmetric Allylic Alkylation”
    Angew. Chem. Int. Ed. 2011, 50, 1877-1881.
  1. A. Quintard, A. Alexakis,
    “1,2-Sulfone rearrangement in organocatalytic reactions”
    Org. Biomol. Chem. 2011, 9, 1407-1418.
  1. C. Hawner, D. Müller, L. Gremaud, A. Felouat, S. Woodward, A. Alexakis,
    “Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Alanes to Trisubstituted Enones: Binap as an Effective Ligand in the Formation of Quaternary Stereocenters”
    Angew. Chem. Int. Ed. 2010, 49, 7769-7772.
  1. Q. Perron, A. Alexakis,
    “Catalytic Asymmetric Bromine-Lithium Exchange: A New Tool to Build Axial Chirality”
    Adv. Synth. Catal. 2010, 352, 2611-2620.
  1. J. Mazuela, O. Pàmies, M. Diéguez, L. Palais, S. Rosset, A. Alexakis,
    “Fine-tunable monodentate phosphoroamidite and aminophosphine ligands for Rh-catalyzed asymmetric hydroformylation”
    Tetrahedron: Asymmetry 2010, 21, 2153-2157.
  1. C. Hawner, A. Alexakis,
    “Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters”
    Chem. Commun. 2010, 46, 7295-7306.
  1. J. Wencel-Delord, A. Alexakis, C. Crévisy, M. Mauduit,
    “Enantioselective 1,6-Conjugate Additionto Cyclic Dienones Catalyzed by theCu-DiPPAM Complex”
    Org. Lett. 2010, 12, 4335-4337.
  1. A. Quintard, A. Alexakis,
    “Highly Enantioselective One-Pot Copper-Catalyzed 1,4 Addition/Organocatalyzed α-Substitution of Enals”
    Adv. Synth. Catal. 2010, 352, 1856-1860.
  1. S. Kehrli, D. Martin, D. Rix, M. Mauduit, A. Alexakis,
    “Formation of Quaternary Chiral Centers by N-Heterocyclic Carbene–Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Trisubstituted Cyclic Enones”
    Chem. Eur. J. 2010, 16, 9890-9904.
  1. C. Bournaud, E. Marchal, A. Quintard, S. Sulzer-Mossé, A. Alexakis,
    “Organocatalyst-mediated enantioselective intramolecular Michael addition of aldehydes to vinyl sulfones”
    Tetrahedron: Asymmetry 2010, 21, 1666-1673.
  1. D. Müller, C. Hawner, M. Tissot, L. Palais, A. Alexakis,
    “Creation of Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Conjugate Addition of Alkenyl Alanes to α,β-Unsaturated Cyclic Ketones”
    Synlett 2010, 1694-1698.
  1. M. Tissot, D. Müller, S. Belot, A. Alexakis,
    “Enantioselective and Regiodivergent Copper-Catalyzed Conjugate Addition of Trialkylaluminium Reagents to Extended Nitro-Michael Acceptors”
    Org. Lett. 2010, 12, 2770-2773.
  1. A. Quintard, A. Alexakis,
    “Asymmetric addition of α-hetero-disubstituted aldehydes to vinyl sulfones; formation of highly functionalized tetrasubstituted carbon centres”
    Chem. Commun. 2010, 46, 4085-4087.
  1. L. Palais, L. Babel, A. Quintard, S. Belot, A. Alexakis,
    “Copper-Catalyzed Enantioselective 1,4-Addition to α,β-Unsaturated Aldehydes”
    Org. Lett. 2010, 12, 1988-1991.
  1. O. Jackowski, A. Alexakis,
    “Copper-Free Asymmetric Allylic Alkylation with Grignard Reagents”
    Angew. Chem. Int. Ed. 2010, 49, 3346-3350.
  1. F. Giacomina, D. Riat, A. Alexakis,
    “ω-Ethylenic Allylic Substrates as Alternatives to Cyclic Substrates in Copper- and Iridium-Catalyzed Asymmetric Allylic Alkylation”
    Org. Lett. 2010, 12, 1156-1159.
  1. S. Belot, A. Quintard, N. Krause, A. Alexakis,
    “Organocatalyzed Conjugate Addition of Carbonyl Compounds to Nitrodienes/Nitroenynes and Synthetic Applications”
    Adv. Synth. Catal. 2010, 352, 667-695.
  1. J.-B. Langlois, A. Alexakis,
    “Copper-Catalyzed Asymmetric Allylic Alkylation of Racemic Cyclic Substrates: Application of Dynamic Kinetic Asymmetric Transformation (DYKAT)”
    Adv. Synth. Catal. 2010, 352, 447-457.
  1. L. Palais, C. Bournaud, L. Micouin, A. Alexakis,
    “Copper-Catalysed Ring Opening of Polycyclic meso-Hydrazines with Trialkylaluminium Reagents and SimplePhos Ligands”
    Chem. Eur. J. 2010, 16, 2567-2573.
  1. A. Quintard, S. Belot, E. Marchal, A. Alexakis,
    “Aminal-Pyrrolidine Organocatalysts - Highly Efficient and Modular Catalysts for α-Functionalization of Carbonyl Compounds”
    Eur. J. Org. Chem. 2010, 927-936.
  1. M. Welker, S. Woodward, A. Alexakis,
    “Tandem Reactions with Chiral Enolates: Preparation of Allylic Alcohols via Trapping with Vinyl Oxiranes”
    Org. Lett. 2010, 12, 576-579.
  1. C. Ladjel, N. Fuchs, L. Gremaud, A. Alexakis,
    “Copper catalysed kinetic resolution of cyclic alkenyl cyclopropane malonate with organoaluminiun and grignard reaggents”
    Synlett 2010, 317-320.
  1. L. Palais, A. Alexakis,
    “Copper-catalyzed asymmetric conjugate addition with Grignard reagents and SimplePhos ligands”
    Tetrahedron: Asymmetry 2009, 20, 2866-2870.
  1. D. Polet, A. Alexakis,
    “Copper-catalyzed enantioselective conjugate addition”
    in The Chemistry of organocopper compounds; Z. Rappoport, I. Marek (Eds.)John Wiley and sons: London, 2009; Chap. 14; p. 693-730.
  1. S. Belot, K.A. Vogt, C. Besnard, N. Krause, A. Alexakis,
    “Enantioselective One-Pot Organocatalytic Michael Addition/Gold-Catalyzed Tandem Acetalization/Cyclization”
    Angew. Chem. Int. Ed. 2009, 48, 8923-8926.
  1. E. Raluy, O. Pàmies, M. Diéguez, S. Rosset, A. Alexakis,
    “Sugar-based phosphite and phosphoroamidite ligands for the Cu-catalyzedasymmetric 1,4-addition to enones”
    Tetrahedron: Asymmetry 2009, 20, 2167-2172.
  1. J. Wencel, M. Mauduit, H. Hénon, S. Kehrli, A. Alexakis,
    “Chiral, Chelating, Hydroxyalkyl and Hydroxyaryl N-Heterocyclic Carbenes: Design, Synthesis, and Application in Copper-Catalyzed Asymmetric Conjugate Addition (Cu-ACA)”
    Aldrichim. Acta 2009, 42, 43-50.
  1. A. Quintard, A. Alexakis,
    “Organocatalytic Addition on 1,2-Bis(sulfone)vinylenes Leading to an Unprecedented Rearrangement”
    Chem. Eur. J. 2009, 15, 11109-11113.
  1. L. Palais, A. Alexakis,
    “Copper-Catalyzed Asymmetric Conjugate Addition with Chiral SimplePhos Ligands”
    Chem. Eur. J. 2009, 15, 10473-10485.
  1. C. Ladjel, N. Fuchs, J. Zhao, G. Bernardinelli, A. Alexakis,
    “New Bifunctional Substrates for Copper-Catalyzed Asymmetric Conjugate Addition Reactions with Trialkylaluminium”
    Eur. J. Org. Chem. 2009, 4949-4955.
  1. E. Raluy, O. Pàmies, M. Diéguez, S. Rosset, A. Alexakis,
    “Furanoside phosphite-phosphoroamidite and diphosphoroamidite ligands for Cu-catalyzed asymmetric 1,4-addition reactions”
    Tetrahedron: Asymmetry 2009, 20, 1930-1935.
  1. K.N. Gavrilov, E.B. Benetskiy, T.B. Grishina, E.A. Rastorguev, M.G. Maksimova, S.V. Zheglov, V.A. Davankov, B. Schäffner, A. Börner, S. Rosset, G. Bailat, A. Alexakis,
    “Bulky P*-Chirogenic Diazaphospholidines as monodentate ligands for asymmetric catalysis”
    Eur. J. Org. Chem. 2009, 3923-3929.
  1. J.-B. Langlois, A. Alexakis,
    “Dynamic kinetic asymmetric transformation in copper catalyzed allylic alkylation”
    Chem. Commun. 2009, 3868-3870.
  1. R. Millet, L. Gremaud, T. Bernardez, L. Palais, A. Alexakis,
    “Copper catalysed asymmetric ring opening reaction of oxabenzonorbornadienes with grignard and aluminium reaggents”
    Synthesis 2009, 2101-2112.
  1. Q. Perron, J. Praz, A. Alexakis,
    “Chiral Bromide-Lithium exchange catalysed by diamines”
    Tetrahedron: Asymmetry 2009, 20, 1004-1007.
  1. R. Millet, T. Bernardez, L. Palais, A. Alexakis,
    “Copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents”
    Tetrahedron Lett. 2009, 50, 3474-3477.
  1. S. Sulzer-Mossé, A. Alexakis, J. Mareda, G. Bollot, G. Bernardinelli, Y. Filinchuk,
    “Enantioselective organocatalytic conjugate addition of aldehydes to vinyl sulfones and vinyl phosphonates as challenging Michael accepptors”
    Chem. Eur. J. 2009, 15, 3204-3220.
  1. D. Polet, X. Rathgeb, C.A. Falciola, J.-B. Langlois, S. El Hajjaji, A. Alexakis,
    “Enantioselective Iridium-catalysed allylic arylation”
    Chem. Eur. J. 2009, 15, 1205-1216.
  1. E.B. Benetskii, V.A. Davankov, P.V. Petrovskii, E.A. Rastorguev, T.B. Grishina, K.N. Gavrilov, S. Rosset, G. Bailat, A. Alexakis,
    “New P-Chiral polyfluoroalkyl phosphoramidite ligand in asymmetric transformations catalysed by palladium and copper complexes”
    Russ. J. Org. Chem. 2008, 44, 1846-1848.
  1. C.A. Falciola, A. Alexakis,
    “High diversity on simple substrates: 1,4 dihalo-2-butenes and other difunctionalised allylic halides for copper-catalysed SN2' reactions”
    Chem. Eur. J. 2008, 14, 10615-10627.
  1. H. Hénon, M. Mauduit, A. Alexakis,
    “Regiodivergent 1,4 versus 1,6 Asymmetric Copper-catalysed conjugate addition”
    Angew. Chem. Int. Ed. 2008, 47, 9122-9124.
  1. C. Hawner, K. Li, V. Cirriez, A. Alexakis,
    “Copper-catalysed asymmetric conjugate addition of aryl aluminium reaggents to trisubstituted enones: construction of aryl-substituted quaternary centers”
    Angew. Chem. Int. Ed. 2008, 47, 8211-8214.
  1. S. Belot, A. Massaro, A. Tenti, A. Mordini, A. Alexakis,
    “Enantioselective organocatalytic conjugate addition of aldehydes to nitrodienes”
    Org. Lett. 2008, 10, 4557-4560.
  1. S. Belot, S. Sulzer-Mossé, S. Kehrli, A. Alexakis,
    “Enantioselective organocatalytic conjugate addition of α-aminoketone to nitroolefins”
    Chem. Commun. 2008, 4694-4696.
  1. A. Quintard, C. Bournaud, A. Alexakis,
    “Diversity-Oriented Synthesis towards Conceptually New Highly Modular Aminal-Pyrrolidine Organocatalysts”
    Chem. Eur. J. 2008, 14, 7504-7507.
  1. Q. Perron, A. Alexakis,
    “Copper-catalysed asymmetric addition of diethylzinc to Boc-protected imines”
    Tetrahedron: Asymmetry 2008, 19, 1871-1874.
  1. A. Alexakis, J.E. Bäckvall, N. Krause, O. Pàmies, M. Diéguez,
    “Enantioselective copper-catalysed conjugate addition and allylic substitution reactions”
    Chem. Rev. 2008, 108, 2796-2823.
  1. C.A. Falciola, A. Alexakis,
    “Copper-Catalyzed Asymmetric Allylic Alkylation”
    Eur. J. Org. Chem. 2008, 3765-3780.
  1. R. Millet, A. Alexakis,
    “Simplephos as efficient ligands for the copper-catalysed kinetic resolution of cyclic vinyloxiranes with grognard reaggents”
    Synlett 2008, 12, 1797-1800.
  1. A. Alexakis, M. Vuagnoux-d'Augustin, D. Martin, S. Kehrli, L. Palais, H. Hénon, C. Hawner,
    “Formation of all-carbon quaternary centers by copper-catalysed asymmetric conjugate addition”
    CHIMIA 2008, 62, 461-464.
  1. C.A. Falciola, K. Tissot-Croset, H. Reyneri, A. Alexakis,
    “β- and γ-disubstituted olefins: susbtrates for copper-catalysed asymmetric allylic substitution”
    Adv. Synth. Catal. 2008, 350, 1090-1100.
  1. A. Alexakis, M. Vuagnoux-d'Augustin, D. Martin, S. Kehrli,
    “Formation of all-carbon chiral quaternary centers by copper catalysed asymmetric cojugate addition”
    Latvija kimijas zurnals 2007, 373-377.
  1. M. Vuagnoux-d'Augustin, A. Alexakis,
    “Influence of the double-bond geometry of the Michael acceptor on copper-catalysed asymmetric conjugate addition”
    Eur. J. Org. Chem. 2007, 5852-5860.
  1. Q. Perron, A. Alexakis,
    “Synthesis and application of a new pseudo C2-symmetric tertiary diamine for the enantioselective addition of MeLi to aromatic imines”
    Tetrahedron: Asymmetry 2007, 18, 2503-2506.
  1. M. Vuagnoux-d'Augustin, A. Alexakis,
    “Copper catalysed asymmetric conjugate addition of trialkylaluminuim reaggents to trisubstituted enones: construction of chiral quaternary centers”
    Chem. Eur. J. 2007, 13, 9647-9662.
  1. D. Polet, A. Alexakis,
    “Asymmetric allylic alkylation catalysed by iridium”
    Chimici Oggi / Chemistry Today 2007, 25, 31-32.
  1. L. Palais, I.S. Mikhel, C. Bournaud, L. Micouin, C.A. Falciola, M. Vuagnoux-d'Augustin, S. Rosset, G. Bernardinelli, A. Alexakis,
    “SimplePhos monodentate ligands: Synthesis and application in copper-catalysed reactions”
    Angew. Chem. Int. Ed. 2007, 46, 7462-7465.
  1. M. Vuagnoux-d'Augustin, A. Alexakis,
    “Tandem asymmetric conjugate addition-enolacetates formation of enantiomerically enriched zinc and aluminium enolates”
    Tetrahedron Lett. 2007, 48, 7408-7412.
  1. S. Sulzer-Mossé, M. Tissot, A. Alexakis,
    “First enantioselective organocatalytic conjugate addition of aldehydes to vinyl phosphonates”
    Org. Lett. 2007, 9, 3749-3752.
  1. A. Alexakis, S. El Hajjaji, D. Polet, X. Rathgeb,
    “Iridium-Catalyzed Asymmetric Allylic Substitution with Aryl Zinc Reagents”
    Org. Lett. 2007, 9, 3393-3395.
  1. M. Vuagnoux-d'Augustin, S. Kehrli, A. Alexakis,
    “Enantioselective copper catalysed conjugate addition to 2- or 3- substituted cyclopent-2-ene-1-ones: Construction of stereogenic quaternary carbon centers”
    Synlett 2007, 2057-2060.
  1. S. Sulzer-Mossé, A. Alexakis,
    “Chiral amines as organocatalysts for asymmetric conjugate addition to nitroolefins and vinyl sulfones via enamine activation”
    Chem. Commun. 2007, 3123-3135.
  1. S. Sulzer-Mossé, M. Laars, K. Kriis, T. Kanger, A. Alexakis,
    “Synthesis and use of 3,3'-bimorpholine derivatives in asymmetric Michael addition and intramolecular aldol reaction”
    Synthesis 2007, 1729-1732.
  1. K. Li, A. Alexakis,
    “Copper-Catalyzed Enantioselective Intramolecular Conjugate Addition/Trapping Reactions: Synthesis of Cyclic Compounds with Multichiral Centers”
    Chem. Eur. J. 2007, 13, 3765-3771.
  1. C.A. Falciola, A. Alexakis,
    “1,4-Dichloro- and 1,4-Dibromo-2-butenes as Substrate for Cu-catalyzed Asymmetric Allylic Substitution”
    Angew. Chem. Int. Ed. 2007, 46, 2619-2622.
  1. R. Millet, A. Alexakis,
    “Copper-catalyzed kinetic resolution of 1,3-cyclohexadiene monoepoxide with Grignard reagents”
    Synlett 2007, 435-438.
  1. K. Li, A. Alexakis,
    “Asymmetric conjugate addition to α-halo enones : Dramatic effect of styrene on the enantioselectivity”
    Angew. Chem. Int. Ed. 2006, 45, 7600-7603.
  1. A.-S. Chauvin, G. Bernardinelli, A. Alexakis,
    “Determination of the absolute configuration of chiral cyclic alcohols using diamine derivatizing agents by 31P NMR spectroscopy”
    Tetrahedron: Asymmetry 2006, 17, 2203-2209.
  1. C.A. Falciola, K. Tissot-Croset, A. Alexakis,
    “β-Disubstituted Allylic Chloride: Substrate for th Cu-Catalyzed Asymmetric SN2' Reaction”
    Angew. Chem. Int. Ed. 2006, 45, 5995-5998.
  1. C. Bournaud, C. Falciola, T. Lecourt, S. Rosset, A. Alexakis, L. Micouin,
    “On the use of phosphramidite ligands in copper-catalyzed asymmetric transformations with trialkylaluminium reagents”
    Org. Lett. 2006, 8, 3581-3584.
  1. S. Mossé, A. Alexakis,
    “Organocatalyzed asymmetric reactions via microwave activation”
    Org. Lett. 2006, 8, 3577-3580.
  1. X. Rathgeb, S. March, A. Alexakis,
    “One-pot conjugate addition-trapping of zinc enolates by activated electrophiles”
    J. Org. Chem. 2006, 71, 5737-5742.
  1. D. Martin, S. Kehrli, M. d'Augustin, H. Clavier, M. Mauduit, A. Alexakis,
    “Copper-catalyzed asymmetric conjugate addition of Grignard reagents to trisubstituted enones. Construction of all-carbon quaternary centers”
    J. Am. Chem. Soc. 2006, 128, 8416-8417.
  1. A.-S. Chauvin, A. Alexakis,
    “Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR”
    Beilstein J. Org. Chem 2006, 2.
  1. S. Mossé, M. Laars, K. Kriis, T. Kanger, A. Alexakis,
    “3,3'-Bimorpholine derivatives as a new class of organocatalysts for asymmetric michael addition”
    Org. Lett. 2006, 8, 2559-2562.
  1. S. Gille, N. Cabello, J.-C. Kizirian, A. Alexakis,
    “A new pseudo C2-symmetric tertiary diamine for the enantioselective addition of MeLi to aromatic imines”
    Tetrahedron: Asymmetry 2006, 17, 1045-1047.
  1. S. Mossé, O. Andrey, A. Alexakis,
    “The use of N-iPr-2,2'-bipyrrolidine derivatives as organocatalysts for asymmetric Michael additions”
    CHIMIA 2006, 60, 216-219.
  1. D. Polet, A. Alexakis, K. Tissot-Croset, C. Corminboeuf, K. Ditrich,
    “Phosphoramidite Ligands in Iridium-Catalyzed Allylic Substitution”
    Chem. Eur. J. 2006, 12, 3596-3609.
  1. A. Alexakis, C. Malan, L. Lea, K. Tissot-Croset, D. Polet, C. Falciola,
    “The copper-catalyzed asymmetric allylic substitution”
    CHIMIA 2006, 60, 124-130.
  1. I.S. Mikhel, G. Bernardinelli, A. Alexakis,
    “Chiral P-monodentate phosphoramidite and phosphite ligands forthe enantioselective Pd-catalyzed allylic alkylation”
    Inorg. Chim. Acta 2006, 359, 1826-1836.
  1. A. Alexakis, D. Polet, C. Bournaud, M. Bonin, L. Micouin,
    “Phophoramidite ligands for the enantioselective iridium-catalyzed asymmetric hydroboration of meso-bicyclic hydrazines”
    Tetrahedron: Asymmetry 2005, 16, 3672-3675.
  1. N. Cabello, J.-C. Kizirian, S. Gille, A. Alexakis, G. Bernardinelli, L. Pinchard, J.-C. Caille,
    “Simple 1,2-Diamine Ligands for Asymmetric Addition of Aryllithium Reagents to Imines”
    Eur. J. Org. Chem. 2005, 4835-4842.
  1. N. Fuchs, M. d’Augustin, M. Humam, A. Alexakis, R. Taras, S. Gladiali,
    “Asymmetric conjugate addition of metal alkyl reagents catalyzed by copper complexes with BINPO, a hemilabile P,O-heterobidentate axially chiral ligand”
    Tetrahedron: Asymmetry 2005, 16, 3143-3146.
  1. K. Li, A. Alexakis,
    “Copper catalyzed tandem asymmetric conjugate addition cyclization reaction in presence of chiral phosphoramidite ligands”
    Tetrahedron Lett. 2005, 46, 8019-8022.
  1. S. Mossé, A. Alexakis,
    “First organocatalyzed asymmetric Michael addition of aldehydes to vinyl sufones”
    Org. Lett. 2005, 7, 4361-4364.
  1. C.L. Winn, F. Guillen, J. Pytkowicz, S. Roland, P. Mangeney, A. Alexakis,
    “Enantioselective copper catalysed 1,4-conjugate addition reactions using chiral N-heterocyclic carbenes”
    J. Organomet. Chem. 2005, 690, 5672-5695.
  1. J.-C. Kizirian, N. Cabello, L. Pinchard, J.-C. Caille, A. Alexakis,
    “Enantioselective addition of MeLi to aromatic imines catalyzed by C2-symmetric tertiary diamine”
    Tetrahedron 2005, 61, 8939-8946.
  1. K. Li, A. Alexakis,
    “Copper catalyzed asymmetric conjugate addition-bromination of α, β unsaturated ketones : a highly effective one pot reaction for the synthesis of chiral α bromo β alkyl ketone”
    Tetrahedron Lett. 2005, 46, 5823-5826.
  1. A. Alexakis, V. Albrow, K. Biswas, M. d'Augustin, O. Prieto, S. Woodward,
    “Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones”
    Chem. Commun. 2005, 2843-2845.
  1. E. Vrancken, A. Alexakis, P. Mangeney,
    “Organolithium chiral Lewis base BF3 : versatile combination for the enantioselective desymmetrisation of meso-epoxides”
    Eur. J. Org. Chem. 2005, 1354-1366.
  1. A. Alexakis, A. Tomassini, O. Andrey, G. Bernardinelli,
    “Diastereoselective alkylation of (Arene)tricarbonyl-chromium and ferrocene complexes using a chiral C2-symmetrical 1,2 diamine as auxiliary”
    Eur. J. Org. Chem. 2005, 1332-1339.
  1. D. Polet, A. Alexakis,
    “Kinetic study of various phosphoramidite ligands in the iridium-catalyzed allylic substitution”
    Org. Lett. 2005, 7, 1621-1624.
  1. L. Cointeaux, A. Alexakis,
    “Enantioselective addition of organolithium reagents to quinoline catalyzed by 1,2-diamines”
    Tetrahedron: Asymmetry 2005, 16, 925-929.
  1. M. d'Augustin, L. Palais, A. Alexakis,
    “Enantioselective copper-catalyzed conjugate addition to trisubstituted cyclohexenones: construction of stereogenic quaternary centers”
    Angew. Chem. Int. Ed. 2005, 44, 1376-1378.
  1. D. Polet, A. Alexakis,
    “Cu-catalyzed asymmetric 1,4-addition of Me3Al to nitroalkenes. Synthesis of (+)-Ibuprofen”
    Tetrahedron Lett. 2005, 46, 1529-1532.
  1. A. Alexakis,
    “The conjugate addition reaction”
    in Transition Metals for Organic Synthesis, Vol. 1; C. Bolm, M. Beller (Eds.)Wiley-VCH, 2004; Ch. 3.8; p. 553-562.
  1. K. Tissot-Croset, D. Polet, S. Gille, C. Hawner, A. Alexakis,
    “Synthesis and use of a phosphoramidite ligand for the copper-catalyzed enantioselective allylic substitution. Tandem allylic substitution-ring closing metathesis”
    Synthesis 2004, 2586-2590.
  1. O. Andrey, A. Alexakis, A. Tomassini, G. Bernardinelli,
    “The use of N-alkyl-2,2'-bipyrrolidine derivatives as organocatalysts for the asymmetric Michael addition of ketones and aldehydes to nitroolefins”
    Adv. Synth. Catal. 2004, 346, 1147-1168.
  1. A. Alexakis, A. Tomassini, S. Leconte,
    “Synthesis and applications of chiral bis-THF in asymmetric synthesis”
    Tetrahedron 2004, 60, 9479-9484.
  1. A. Alexakis, D. Polet,
    “Very efficient phosphoramidite ligand for asymmetric iridium-catalyzed allylic alkylation”
    Org. Lett. 2004, 6, 3529-3552.
  1. K. Tissot-Croset, A. Alexakis,
    “Copper catalyzed enantioselective allylic substitution by MeMgX”
    Tetrahedron Lett. 2004, 45, 7375-7378.
  1. A. Alexakis, D. Polet, S. Rosset, S. March,
    “Biphenol-based phosphoramidite ligands for the enantioselective copper-catalyzed conjugate addition of diethylzinc”
    J. Org. Chem 2004, 69, 5660-5667.
  1. A. Alexakis, D. Polet, C. Benhaim, S. Rosset,
    “Biphenol-based ligands for Cu-catalyzed asymmetric conjugate addition”
    Tetrahedron: Asymmetry 2004, 15, 2199-2203.
  1. F. Amiot, L. Cointeaux, E.J. Silve, A. Alexakis,
    “Enantioselective nucleophilic addition of organometallic reagents to quinoline: regio-, stereo- and enantioselectivity”
    Tetrahedron 2004, 60, 8221-8231.
  1. A. Alexakis,
    “Asymmetric organocopper chemistry: Cu-catalyzed conjugate addition and allylic substitution”
    in Methodologies in Asymmetric Catalysis; S.V. Malhotra (Ed.)ACS Symposium Series, Volume 880: Washington, 2004; Ch. 4; p. 43-59.
  1. A.-S. Chauvin, G. Bernardinelli, A. Alexakis,
    “Determination of the Absolute Configuration of Chiral Aryl-alkyl Carbinols using Organophosphorous Diamine Derivatizing Agents by 31P NMR Spectroscopy”
    Tetrahedron: Asymmetry 2004, 15, 1857-1879.
  1. A.M. Arink, T.W. Braam, R. Keeris, J.T.B.H. Jastrzebski, C. Benhaim, S. Rosset, A. Alexakis, G. van Koten,
    “Copper(I) thiolate catalysts in asymmetric conjugate addition reactions”
    Organic Lett. 2004, 6, 1959-1962.
  1. N. Cabello, J.-C. Kizirian, A. Alexakis,
    “Enantioselective addition of aryllithium reagents to aromatic imines mediated by 1,2-diamine ligands”
    Tetrahedron Lett. 2004, 45, 4639-4642.
  1. O. Equey, A. Alexakis,
    “Enantioselective opening of cyclic vinyl epoxides with organoaluminium reagents catalysed by copper salts”
    Tetrahedron: Asymmetry 2004, 15, 1531-1536.
  1. O. Equey, E. Vrancken, A. Alexakis,
    “Regioselective SN2 opening of vinylic epoxides with trialkylzincates and tetralkylaluminates”
    Eur. J. Org. Chem. 2004, 2151-2159.
  1. K. Tissot-Croset, D. Polet, A. Alexakis,
    “A highly effective phosphoramidite ligand for asymmetric allylic substitution”
    Angew. Chem. Int. Ed. 2004, 43, 2426-2428.
  1. O. Equey, A. Alexakis,
    “Enantioselective catalytic rearrangement of cyclohexene oxide with new homochiral bis-lithium amide bases”
    Tetrahedron: Asymmetry 2004, 15, 1069-1072.
  1. A. Alexakis, S. Gille, F. Prian, S. Rosset, K. Ditrich,
    “Practical, solvent-free, one-pot synthesis of C2-symmetrical secondary amines”
    Tetrahedron Lett. 2004, 45, 1449-1451.
  1. J.-C. Kizirian, J.-C. Caille, A. Alexakis,
    “Conceptually new chiral tertiary C2 symmetric diamines in asymmetric synthesis”
    Tetrahedron Lett. 2003, 44, 8893-8895.
  1. O. Andrey, A. Vidonne, A. Alexakis,
    “Organocatalytic Michael addition, a convenient tool in total synthesis. First asymmetric synthesis of (-)-botryodiplodin”
    Tetrahedron Lett. 2003, 44, 7901-7904.
  1. O. Andrey, A. Alexakis, G. Bernardinelli,
    “Asymmetric Michael addition of α-hydroxy aldehydes to nitroolefins catalyzed by chiral diamine”
    Org. Lett. 2003, 5, 2559-2561.
  1. A. Alexakis, C.L. Winn, F. Guillen, J. Pytkowicz, S. Roland, P. Mangeney,
    “Asymmetric synthesis with N-heterocyclic carbenes. Application to the copper catalyzed conjugate addition”
    Adv. Synth. Catal. 2003, 345, 345-348.
  1. A. Alexakis, S. March,
    “Tandem enantioselective conjugate addition-cyclopropanation. Application to natural product synthesis”
    J. Org. Chem 2002, 67, 8753-8757.
  1. A. Alexakis, O. Andrey,
    “Diamine-catalyzed asymmetric Michael additions of aldehydes and ketones to nitrostyrene”
    Org. Lett. 2002, 4, 3611-3614.
  1. A. Alexakis, F. Amiot,
    “Enantioselective addition of organolithium reagents on isoquinoline”
    Tetrahedron: Asymmetry 2002, 13, 2117-2122.
  1. A. Alexakis, K. Croset,
    “Tandem Copper-Catalyzed Enantioselective Allylation-Metathesis”
    Org. Lett. 2002, 4, 4147-4149.
  1. O. Knopff, A. Alexakis,
    “Tandem asymmetric conjugate addition-silylation of enantiomerically enriched zinc enolates. Synthetic importance and mechanistic implications”
    Org. Lett. 2002, 4, 3835-3837.
  1. L. Mediavilla Urbaneja, A. Alexakis, N. Krause,
    “Epimerization and kinetic resolution in copper-catalyzed enantioselective 1,4-additions of organozinc reagents to 6-substituted cyclohex-2-enones”
    Tetrahedron Lett. 2002, 43, 7887-7890.
  1. A. Alexakis, C. Benhaim,
    “Enantioselective Copper-Catalysed Conjugate Addition”
    Eur. J. Org. Chem. 2002, 3221-3236.
  1. A. Alexakis, C. Benhaim, S. Rosset, M. Humam,
    “Dramatic enhancement of the enantiomeric excess in asymmetric conjugate addition reaction using new experimental conditions”
    J. Am. Chem. Soc. 2002, 124, 5262-5263.
  1. A. Alexakis,
    “Copper-mediated asymmetric transformations”
    Pure & Appl. Chem. 2002, 74, 37-42.
  1. F. Guillen, C.L. Winn, A. Alexakis,
    “Enantioselective copper-catalyzed conjugate addition using chiral diaminocarbene ligands”
    Tetrahedron: Asymmetry 2001, 12, 2083-2086.
  1. A. Alexakis, S. Rosset, J. Allamand, S. March, F. Guillen, C. Benhaim,
    “Novel biphenol phosphoramidite ligands for the enantioselective copper-catalyzed conjugate addition of dialkyl zincs”
    Synlett 2001, 1375-1378.
  1. F. Mazé, M. Purpura, F. Bernaud, P. Mangeney, A. Alexakis,
    “Regio- and diastereoselective SN2' or SN2'' reactions on chiral acetals of cyclic aldehydes promoted by PhCu, BF3”
    Tetrahedron: Asymmetry 2001, 12, 1957-1960.
  1. A. Alexakis, A.-S. Chauvin,
    “Determination of the enantiomeric excess of chiral carboxylic acids by 31P NMR with C2 symmetrical diamines”
    Tetrahedron: Asymmetry 2001, 12, 1411-1415.
  1. A. Alexakis, A.-S. Chauvin, R. Stouvenel, E. Vrancken, S. Mutti, P. Mangeney,
    “A practical and efficient synthesis of chiral N,N-disubstituted C2 symmetric diamines derived from (R,R)-1,2-diaminocyclohexane”
    Tetrahedron: Asymmetry 2001, 12, 1171-1178.
  1. A. Alexakis, C. Benhaim,
    “Asymmetric conjugate addition to alkylidene malonates”
    Tetrahedron: Asymmetry 2001, 12, 1151-1157.
  1. A. Alexakis, C. Malan, L. Lea, C. Benhaim, X. Fournioux,
    “Enantioselective copper-catalyzed SN2' substitution with Grignard reagents”
    Synlett 2001, 927-930.
  1. A. Alexakis, I. Aujard, J. Pytkowicz, S. Roland, P. Mangeney,
    “Unusually facile palladium catalysed oxidation of imidazolidines and oxazolidines”
    J. Chem. Soc., Perkin Trans. 1 2001, 949-951.
  1. A. Alexakis, G.P. Trevitt, G. Bernardinelli,
    “Tandem enantioselective conjugate addition-electrophile trapping reactions. Application in the formation of syn or anti aldols”
    J. Am. Chem. Soc. 2001, 123, 4358-4359.
  1. A. Alexakis, J. Burton, J. Vastra, C. Benhaim, X. Fournioux, A. van den Heuvel, J.-M. Levêque, F. Mazé, S. Rosset,
    “Synthesis and application of chiral phosphorus ligands derived from TADDOL for the asymmetric conjugate addition of diethylzinc to enones”
    Eur. J. Org. Chem. 2000, 4011-4027.
  1. A. Alexakis, A.-S. Chauvin,
    “TADDOL organophosphorus derivatising agents for the determination of the enantiomeric excess of alcohols and carboxylic acids by 31P and 1H NMR spectroscopy”
    Tetrahedron: Asymmetry 2000, 11, 4245-4248.
  1. A. Alexakis, A. Tomassini, C. Chouillet, S. Roland, P. Mangeney, G. Bernardinelli,
    “A new efficient synthesis of (R,R)-2,2'-bipyrrolidine: an interesting chiral 1,2-diamine with C2 symmetry.”
    Angew. Chem. Int. Ed. 2000, 39, 4093-4095.
  1. A. Alexakis, E. Vrancken, P. Mangeney,
    “Effect of BF3·Et2O reagent on the base-promoted rearrangements of epoxides attached to eight-membered rings”
    J. Chem. Soc., Perkin Trans. 1 2000, 3354-3355.
  1. A. Alexakis, E. Vrancken, P. Mangeney, F. Chemla,
    “Regioselective SN2 opening of α,β-ethylenic epoxides by RLi-BF3 combination”
    J. Chem. Soc., Perkin Trans. 1 2000, 3352-3353.
  1. A. Alexakis, C. Benhaim,
    “Enantioselective copper-catalyzed conjugate addition of dialkylzinc to nitro-olefins”
    Org. Lett. 2000, 2, 2579-2581.
  1. A. Alexakis,
    “Asymmetric synthesis using organocopper reagents”
    CHIMIA 2000, 54, 55-56.
  1. A. Alexakis, C. Benhaïm, X. Fournioux, A. van den Heuvel, J.-M. Levêque, S. March, S. Rosset,
    “Catalytic asymmetric conjugate addition on macrocyclic and acyclic enones. Synthesis of R-(-)-Muscone”
    Synlett 1999, 1811-1813.
  1. F. Rose-Munch, V. Gagliardini, A. Perrotey, J.-P. Tranchier, E. Rose, P. Mangeney, A. Alexakis, T. Kanger, J. Vaissermann,
    “Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex”
    Chem. Commun. 1999, 2061-2062.
  1. F. Rezgui, P. Mangeney, A. Alexakis,
    “Asymmetric synthesis of 1,2- and 1,4-dihydroquinolines”
    Tetrahedron Lett. 1999, 40, 6241-6244.
  1. S. Roland, P. Mangeney, A. Alexakis,
    “A practical and efficient synthesis of enantiomerically pure di-tert-butyl-ethanediamine”
    Synthesis 1999, 228-230.
  1. A. Alexakis,
    “Copper (I) promoted asymmetric transformations : a long standing challenge”
    in Transition Metal Catalysed Reactions; S.-I. Murahashi, S.G. Davies (Eds.)Blackwell Science, IUPAC: Oxford, 1999; Ch. 15; p. 303-316.
  1. A. Alexakis, I. Aujard, T. Kanger, P. Mangeney,
    “(R,R)- and (S,S)-N,N'-dimethyl-1,2-diphenylethylene-1,2-diamine”
    Org. Synth. 1999, 76, 23-36.
  1. A. Alexakis,
    “The conjugate addition reaction”
    in Transition Metals for Organic Synthesis, Vol. 1; M. Beller, C. Bolm (Eds.)Wiley-VCH: Weinheim, 1998; Ch. 3.10; p. 504-513.
  1. A. Alexakis, J. Vastra, J. Burton, C. Benhaim, P. Mangeney,
    “Asymmetric conjugate addition of diethylzinc to enones with chiral phosphorus ligands derived from TADDOL”
    Tetrahedron Lett. 1998, 39, 7869-7872.
  1. A. Alexakis, E. Vrancken, P. Mangeney,
    “Enantioselective nucleophilic opening of meso epoxides by organolithium reagents”
    Synlett 1998, 1165-1167.
  1. P. Mangeney, L. Hamon, S. Raussou, N. Urbain, A. Alexakis,
    “Radical cyclizations of 1,4-dihydropyridines. Synthesis of chiral fused nitrogen heterocycles. Synthesis of Lupinine and Epilupinine”
    Tetrahedron 1998, 54, 10349-10362.
  1. A. Alexakis, I. Aujard, P. Mangeney,
    “Isomerization of meso diamines into their C2 symmetrical d,l isomers”
    Synlett 1998, 875-876.
  1. A. Alexakis, I. Aujard, P. Mangeney,
    “Practical and efficient synthesis of C2 symmetrical diamines with Zn/Me3SiCl”
    Synlett 1998, 873-874.
  1. D. Brasseur, H. Rezaei, A. Fuxa, A. Alexakis, P. Mangeney, I. Marek, J.F. Normant,
    “First diastereoselective asymmetric carbometallation of chiral vinyl metals”
    Tetrahedron Lett. 1998, 39, 4821-4824.
  1. A. Alexakis, J. Burton, J. Vastra, P. Mangeney,
    “Asymmetric conjugate addition of diethyl zinc to enones with chiral phosphine ligands”
    Tetrahedron: Asymmetry 1997, 8, 3987-3990.
  1. A. Alexakis, J. Vasta, P. Mangeney,
    “Acceleration of the conjugate addition of diethyl zinc to enones by either Cu(OTf)2 or trivalent phosphorus ligands”
    Tetrahedron Lett. 1997, 38, 7745-7748.
  1. A. Alexakis, J. Varta, J. Burton, P. Mangeney,
    “Asymmetric conjugate addition of diethyl zinc to enones with tartrate chiral phosphite ligands”
    Tetrahedron: Asymmetry 1997, 8, 3193-3196.
  1. F.M. Bohnen, R. Goddard, A.B.E. Minidis, A. Alexakis, A. Pfaltz,
    “A copper (II) complex of a new chiral tridentate imidazoline ligand”
    Acta Crystallographica 1997, C53, 1236-1238.
  1. J.P. Tierney, A. Alexakis, P. Mangeney,
    “Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases”
    Tetrahedron: Asymmetry 1997, 8, 1019-1022.
  1. A. Alexakis, F. Mhamdi, F. Lagasse, P. Mangeney,
    “Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents”
    Tetrahedron: Asymmetry 1996, 7, 3343-3346.
  1. H. Rakotoarisoa, R. Guttierez Perez, P. Mangeney, A. Alexakis,
    “Remote asymmetric induction. New mechanistic insights concerning the SN' and SN" substitution in organocopper chemistry”
    Organometallics 1996, 15, 1957-1959.
  1. S. Raussou, N. Urbain, P. Mangeney, A. Alexakis, N. Platzer,
    “Preparation of chiral hexahydroquinolizinones and tetrahydroindolizinones by regio- and diastereoselective sonochemical cyclization of chiral dihydropyridines”
    Tetrahedron Lett. 1996, 37, 1599-1602.
  1. A. Alexakis, P. Mangeney, N. Lensen, J.-P. Tranchier, R. Gosmini, S. Raussou,
    “Chiral Aminals: Powerful auxiliaries in asymmetric synthesis”
    Pure Appl. Chem. 1996, 68, 531-534.
  1. A. Alexakis, P. Mangeney,
    “Chiral aminals in asymmetric synthesis”
    in Advanced Asymmetric Synthesis; G.R. Stephenson (Ed.)Chapman & Hall: London, 1996; Ch. 5; p. 93-110.
  1. A. Alexakis, J.-P. Tranchier, N. Lensen, P. Mangeney,
    “Monoaminals of glyoxal : versatile chirons”
    J. Am. Chem. Soc. 1995, 117, 10767-10768.
  1. A. Alexakis, T. Kanger, P. Mangeney, F. Rose-Munch, A. Perrotey, E. Rose,
    “Enantioselective ortho-lithiation of benzaldehyde chromiumtricarbonyl complex”
    Tetrahedron: Asymmetry 1995, 6, 2135-2138.
  1. A. Alexakis, N. Lensen, J.-P. Tranchier, P. Mangeney, J. Feneau-Dupont, J.-P. Declercq,
    “Chiral aminal templates: Diastereoselective addition to hydrazones; an asymmetric synthesis of α-amino aldehydes”
    Synthesis 1995, 1038-1050.
  1. J.-M. Duffault, J. Einhorn, A. Alexakis,
    “Synthesis of regioselectively deuterated hydroxy conjugated dienes”
    Tetrahedron Lett. 1995, 36, 2765-2768.
  1. A. Alexakis, P. Mangeney,
    “Chiral diamines in asymmetric synthesis”
    Acros Chimica Acta 1995, 1, 22-23.
  1. A. Alexakis, T. Kanger, P. Mangeney, F. Rose-Munch, A. Perrotey, E. Rose,
    “Enantioselective ortho-lithiation of aminals of benzaldehyde chromiumtricarbonyl complex”
    Tetrahedron: Asymmetry 1995, 6, 47-50.
  1. A. Alexakis,
    “Asymmetric conjugate addition”
    in Organocopper Reagents; R.J.K. Taylor (Ed.)Oxford University Press, 1994; Ch. 8; p. 159-193.
  1. A. Alexakis, J.C. Frutos, P. Mangeney, A.I. Meyers, H. Moorlag,
    “Determination of enantiomeric purity of hydroxy biaryls using 1H and 31P NMR on their diazaphospholidine derivatives”
    Tetrahedron Lett. 1994, 35, 5125-5128.
  1. S. Raussou, R. Gosmini, P. Mangeney, A. Alexakis, M. Commerçon,
    “Regio and enantioselective synthesis of 4-carbomethoxymethy-1,4-dihydropyridines”
    Tetrahedron Lett. 1994, 35, 5433-5436.
  1. A. Alexakis, J.C. Frutos, S. Mutti, P. Mangeney,
    “Chiral diamines for a new protocol to determine the enantiomeric composition of alcohols, thiols and amines by 31P, 1H, 13C and 19F NMR”
    J. Org. Chem. 1994, 59, 3326-3334.
  1. P. Mangeney, R. Gosmini, S. Raussou, M. Commercon, A. Alexakis,
    “Preparation and utilization of chiral dihydropyridines. Synthesis of chiral indoloquinolizines and benziquinolizines”
    J. Org. Chem. 1994, 59, 1877-1888.
  1. A. Alexakis, J.C. Frutos, P. Mangeney,
    “An easy and fast way to determine the enantiomeric purity of substituted cyclanones”
    Tetrahedron: Asymmetry 1993, 4, 2431-2434.
  1. A. Alexakis, J. Frutos, P. Mangeney,
    “Chiral phosphorus ligands for the asymmetric conjugate addition of organocopper reagents”
    Tetrahedron: Asymmetry 1993, 4, 2427-2430.
  1. A. Alexakis, R. Sedrani, N. Lensen, P. Mangeney,
    “Chiral aminal templates. Diastereo- and enantioselectivity in 1,4 (conjugate) and 1,2 additions with organometallic reagents”
    in Organic Synthesis via Organometallics; D. Enders, H.-J. Gais, W. Keim (Eds.)Vieweg: Wiesbaden, 1993; p. 1-9.
  1. A. Alexakis, P. Mangeney, I. Marek, F. Rose-Munch, E. Rose, A. Semra, F. Robert,
    “Resolution and asymmetric synthesis of ortho-substituted benzaldehydetricarbonylchromium complexes”
    J. Am. Chem. Soc. 1992, 114, 8288-8290.
  1. A. Alexakis, N. Lensen, J.-P. Tranchier, P. Mangeney,
    “Reactivity and diastereoselectivity of Grignard reagents toward the hydrazone functionality in toluene solvent”
    J. Org. Chem. 1992, 57, 4563-4565.
  1. A. Alexakis, A.-M. Barthel, J.F. Normant, C. Fugier, M. Leroux,
    “A new efficient and stereoselective synthesis of 1,3E, 5Z-undecatriene”
    Synthetic Communications 1992, 22, 1839-1844.
  1. I. Marek, A. Alexakis, P. Mangeney, J.F. Normant,
    “Synthèse d'alcoxy-allènes chiraux par carbocupration d'acétals propargyliques. Etude de leur réactivité à l'égard d'organocuprates”
    Bull. Soc. Chim. Fr. 1992, 129, 171-190.
  1. A. Alexakis,
    “Stereochemical aspects on the formation of chiral allenes from propargylic ethers and epoxides”
    Pure Appl. Chem. 1992, 64, 387-392.
  1. A. Alexakis, S. Mutti, P. Mangeney,
    “A new reagent for the determination of the optical purity of primary, secondary and tertiary chiral alcohols and of thiols”
    J. Org. Chem. 1992, 57, 1224-1237.
  1. G. Courtemanche, A. Alexakis, J. Vaissermann, J.F. Normant,
    “Conjugate addition of organocuprates on γ-methyl-δ-oxy-α,β-enones. Influence of the alkoxy substituent on the diastereoselection”
    J. Organomet. Chem. 1992, 423, 238-305.
  1. I. Marek, A. Alexakis, J.F. Normant,
    “γ-Tributylstannyl-β-metallated acrolein : a versatile synthon”
    Tetrahedron Lett. 1991, 32, 6337-6340.
  1. I. Marek, A. Alexakis, J.-F. Normant,
    “A highly efficient synthesis of (Z) γ-iodo allylic alcohols”
    Tetrahedron Lett. 1991, 32, 5329-5332.
  1. A. Alexakis, N. Lensen, P. Mangeney,
    “Ultrasound assisted cleavage of hydrazines by Raney nickel”
    Synlett 1991, 625-626.
  1. A. Alexakis, S. Mutti, P. Mangeney, J.F. Normant,
    “A new chiral ligand for the asymmetric conjugate addition of organocopper reagents to enones”
    J. Am. Chem. Soc. 1991, 113, 6332-6334.
  1. P. Mangeney, R. Gosmini, A. Alexakis,
    “Enantioselective synthesis of indoloquinolizidines”
    Tetrahedron Lett. 1991, 32, 3981-3984.
  1. J.-M. Duffault, J. Einhorn, A. Alexakis,
    “Expeditions synthesis of the four isomers of methyl dimorphecolate”
    Tetrahedron Lett. 1991, 32, 3701-3704.
  1. A. Alexakis, N. Lensen, P. Mangeney,
    “Chiral aminal templates 6. Diastereoselectivity of hydrazo-ne alkylation. Asymmetric synthesis of α-amino-aldehydes”
    Tetrahedron Lett. 1991, 32, 1171-1174.
  1. A. Alexakis, I. Marek, P. Mangeney, J.F. Normant,
    “Diastereoselective syn or anti opening of propargylic epoxides. Synthesis of α-allenic alcohols”
    Tetrahedron 1991, 47, 1677-1696.
  1. R. Gosmini, P. Mangeney, A. Alexakis, M. Commerçon, J.F. Normant,
    “Chiral aminal templates 5. Preparation of chiral 3-carboxaldehydes-1,4-dihydropyridines”
    Synlett 1991, 111-113.
  1. A. Alexakis, P. Mangeney,
    “Chiral acetals in asymmetric synthesis”
    Tetrahedron: Asymmetry 1990, 1, 477-511.
  1. A. Alexakis, S. Mutti, J.F. Normant, P. Mangeney,
    “A new reagent for a very simple and efficient determination of enantiomeric purity of alcohols by 31P NMR”
    Tetrahedron: Asymmetry 1990, 1, 437-440.
  1. A. Alexakis, I. Marek, P. Mangeney, J.F. Normant,
    “Mechanistic aspects on the formation of chiral allenes from propargylic ethers and organocopper reagents”
    J. Am. Chem. Soc. 1990, 112, 8042-8047.
  1. J.F. Normant, J.C. Quirion, Y. Masuda, A. Alexakis,
    “Reactivity of allyl-zinc (and copper) reagents towards allenic ethers and α-metallated allenic ethers”
    Tetrahedron Lett. 1990, 31, 2879-2882.
  1. M. Commerçon, P. Mangeney, T. Tejero, A. Alexakis,
    “Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes”
    Tetrahedron: Asymmetry 1990, 1, 287-289.
  1. A. Alexakis, R. Sedrani, J.F. Normant, P. Mangeney,
    “Chiral aminal templates 3. Diastereoselectivity of organo-metallic attack on aldehydes bearing a chiral imidazolidine group”
    Tetrahedron: Asymmetry 1990, 1, 283-286.
  1. A. Alexakis, J. Hanaïzi, D. Jachiet, J.F. Normant,
    “Unusual 1,2-migration in organoaluminium chemistry, promoted by BF3.OEt2”
    Tetrahedron Lett. 1990, 31, 1271-1274.
  1. A. Alexakis, R. Sedrani, P. Mangeney,
    “Stereochemical effects of trimethylsilyl chloride (TMSCl) on the conjugate addition of organocopper reagents”
    Tetrahedron Lett. 1990, 31, 345-348.
  1. A. Alexakis, D. Jachiet,
    “A completely stereoselective intramolecular Diels-Alder reaction in the substituted cyclohexanol series”
    Tetrahedron 1989, 45, 6203-6210.
  1. A. Alexakis, D. Jachiet,
    “Boron trifluoride assisted opening of epoxides by lithium alkenyl aluminate reagents”
    Tetrahedron 1989, 45, 6197-6202.
  1. J.F. Normant, J.C. Quirion, A. Alexakis, Y. Masuda,
    “Allylic organobismetallic reagents - Part 1”
    Tetrahedron Lett. 1989, 30, 3955-3958.
  1. A. Alexakis, I. Marek, P. Mangeney, J.F. Normant,
    “Copper catalyzed reductive metallation of a propargylic epoxide to an allenyl lithium reagent”
    Tetrahedron Lett. 1989, 30, 2391-2392.
  1. A. Alexakis, I. Marek, P. Mangeney, J.F. Normant,
    “Diastereoselective synthesis of α-allenic alcohols from propargylic epoxides”
    Tetrahedron Lett. 1989, 30, 2387-2390.
  1. D. Cuvinot, P. Mangeney, A. Alexakis, J.F. Normant, J.P. Lellouche,
    “Chiral trifluoro diamines as convenient reagents for determining the enantiomeric purity of aldehydes by use of 19F NMR spectroscopy”
    J. Org. Chem. 1989, 54, 2420-2425.
  1. J.F. Normant, A. Alexakis, A. Ghribi, P. Mangeney,
    “Boron fluoride promoted cleavage of acetals by organocopper reagents. Application to asymmetric synthesis”
    Tetrahedron 1989, 45, 507-516.
  1. A. Alexakis, D. Jachiet,
    “A new approach to conjugate dienes. Synthesis of the pheromones of Lobesia Botrana and Bombyx Mori”
    Tetrahedron 1989, 45, 381-389.
  1. A. Alexakis, J.-M. Duffault,
    “The hydroalumination of ω-terbutoxy alkynes an easy access to ω-hydroxy alkenyl iodides. Application to the synthesis of dienic insect pheromone”
    Tetrahedron Lett. 1988, 29, 6243-6246.
  1. A. Alexakis, P. Mangeney, A. Ghribi, D. Jachiet, J.F. Normant,
    “Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage”
    Philosoph. Trans. Royal Society, London 1988, 326, 557-564.
  1. A. Alexakis, R. Sedrani, P. Mangeney, J.F. Normant,
    “Diastereoselective conjugate addition with acetals, oxazolidines and imidazolidines as chiral auxiliaries”
    Tetrahedron Lett. 1988, 29, 4411-4414.
  1. A. Alexakis, M. Gardette, S. Colin,
    “Mild protection and deprotection of alcohols as ter-butyl ethers in the field of pheromone synthesis”
    Tetrahedron Lett. 1988, 29, 2951-2954.
  1. P. Mangeney, A. Alexakis, J.F. Normant,
    “Resolution and determination of enantiomeric excesses of chiral aldehydes via chiral imidazolidines”
    Tetrahedron Lett. 1988, 29, 2677-2680.
  1. P. Mangeney, A. Alexakis, J.F. Normant,
    “Improved optical resolution of R*,R* N,N'-dimethyl 1,2-diphenyl ethylene diamine”
    Tetrahedron Lett. 1988, 29, 2675-2676.
  1. A. Alexakis, D. Jachiet,
    “A new strategy for the synthesis of the pheromones of Lobesia Botrana and Bombyx Mori”
    Tetrahedron Lett. 1988, 29, 217-218.
  1. C. Fugier, M. Leroux, R. Mauge, A. Alexakis, J.F. Normant,
    “Nouveau procédé de préparation énantiospécifique du (S) éthylamino-2 (trifluorométhyl-3 phényl)-1 propane”
    Brevet d'Invention 1988, n° 5614.
  1. P. Mangeney, T. Tejero, A. Alexakis, F. Grosjean, J.F. Normant,
    “Titanium induced coupling of imines to symmetrical vicinal (R*,R*)-diamines”
    Synthesis 1988, 255-259.
  1. A. Alexakis, P. Mangeney, A. Ghribi, I. Marek, R. Sedrani, C. Guir, J.-F. Normant,
    “Chiral acetals in enantio- and diastereoselective substitution or elimination reactions”
    Pure Appl. Chem. 1988, 60, 49-56.
  1. P. Mangeney, A. Alexakis, J.F. Normant,
    “Acetals as chiral auxiliaries. Part 4. Asymmetric synthesis of γ,δ-ethylenic aldehydes. An approach to the California Red Scale Pheromone”
    Tetrahedron Lett. 1987, 28, 2363-2366.
  1. A. Alexakis,
    “La carbocupration: un puissant outil de synthèse de phéromones sexuelles d'insectes”
    L'actualité Chimique 1987, 203-217.
  1. A. Alexakis, D. Jachiet, J.F. Normant,
    “Boron fluoride promoted opening of epoxides by organocopper or cuprates reagents”
    Tetrahedron 1986, 42, 5607-5619.
  1. I. Marek, P. Mangeney, A. Alexakis, J.F. Normant,
    “Are allenes formed from propargylic ethers through a syn or anti displacement α”
    Tetrahedron Lett. 1986, 27, 5499-5502.
  1. C. Fugier, M. Leroux, J.F. Normant, A. Alexakis,
    “Nouveau procédé de préparation des undécatriènes-1,3,5”
    Brevet d'invention Européen 1986, n° 86 107 380.7.
  1. P. Mangeney, A. Alexakis, J.F. Normant,
    “Diastereoselective conjugate addition to chiral α,β-ethylenic acetals”
    Tetrahedron Lett. 1986, 27, 3143-3146.
  1. N. Jabri, A. Alexakis, J.F. Normant,
    “Palladium mediated synthesis of conjugate (E) or (Z) enones and unsymmetrical divinyl ketones. One-pot preparation of Isoegomaketone”
    Tetrahedron 1986, 42, 1369-1380.
  1. A. Alexakis, J. Berlan, Y. Besace,
    “Organocopper conjugate addition reaction in the presence of trimethylchlorosilane”
    Tetrahedron Lett. 1986, 27, 1047-1050.
  1. M. Gardette, A. Alexakis, J.F. Normant,
    “Alkenyl copper reagents 26. Carbocupration of alkynes by reagents bearing a protected hydroxy or thiol function”
    Tetrahedron 1985, 41, 5887-5899.
  1. A. Alexakis, P. Mangeney, J.F. Normant,
    “Diastereoselective β-elimination. Synthesis of chiral alkoxy-allenes”
    Tetrahedron Lett. 1985, 26, 4197-4200.
  1. C. Fugier, M. Leroux, J.F. Normant, A. Alexakis,
    “Nouveau procédé de préparation des undécatriènes”
    Brevet d'invention, Institut National de la Propriété Industrielle 1985, n° 85 08181.
  1. A. Alexakis, J.F. Normant,
    “Alkenylcopper Derivatives; 27. Synthesis of 1-Alkenyl Thioethers by Cleavage of Disulfides with 1-Alkenyl-copper Reagents”
    Synthesis 1985, 72-74.
  1. C. Germon, A. Alexakis, J.F. Normant,
    “Alkenyl copper derivatives 28. Stereospecific synthesis of tertiary allylic amines of (E) or (Z) configuration”
    Bull. Soc. Chim. France II 1984, 377-389.
  1. M. Gardette, N. Jabri, A. Alexakis, J.F. Normant,
    “General methodology for the synthesis of conjugated dienic insect sex pheromones”
    Tetrahedron 1984, 40, 2741-2750.
  1. A. Alexakis, J.F. Normant,
    “Alkenyl copper derivatives 25. Synthesis of (E) or (Z) enol ethers by carbocupration of alkoxy-allenes”
    Israel J. Chem. 1984, 24, 113-117.
  1. A. Ghribi, A. Alexakis, J.F. Normant,
    “Asymmetric cleavage of chiral acetals by R2CuLi,BF3 reagents”
    Tetrahedron Lett. 1984, 25, 3083-3086.
  1. A. Ghribi, A. Alexakis, J.F. Normant,
    “Reactivity of RCu,BF3 and R2CuLi,BF3 towards allylic acetals and ethers”
    Tetrahedron Lett. 1984, 25, 3079-3082.
  1. A. Ghribi, A. Alexakis, J.F. Normant,
    “Reactivity of RCu,BF3 and R2CuLi,BF3 toward the ether linkage. Epoxides, acetals and orthoformates”
    Tetrahedron Lett. 1984, 25, 3075-3078.
  1. P. Mangeney, A. Alexakis, J.F. Normant,
    “Etude d'un modele d'induction asymetrique: Les oxazolidines α,β-insaturées issues de l'éphédrine”
    Tetrahedron 1984, 40, 1803-1808.
  1. A. Alexakis, A. Commercon, C. Coulentianos, J.F. Normant,
    “Alkenyl copper reagents - 18. Carbocupration of acetylenic acetals and ketals. Synthesis of manicone, geranial and 2,4-(E,Z)-dienals”
    Tetrahedron 1984, 40, 715-731.
  1. G. Friour, A. Alexakis, G. Cahiez, J. Normant,
    “Reactivity of organomanganese derivatives. VIII. Preparation of ketones by acylation of organomanganese compounds. Effect of acylating agent, solvents, and ligands”
    Tetrahedron 1984, 40, 683-693.
  1. A. Alexakis, C. Chuit, M. Commercon-Bourgain, J.P. Foulon, N. Jabri, P. Mangeney, J.F. Normant,
    “Organocopper reagents for the synthesis of saturated, and a,b-ethylenic aldehydes and ketones”
    Pure Appl. Chem. 1984, 56, 91-98.
  1. C. Germon, A. Alexakis, J.F. Normant,
    “Alkenylcopper derivatives; 22. Stereoselective synthesis of allylic thioethers”
    Synthesis 1984, 43-46.
  1. C. Germon, A. Alexakis, J.F. Normant,
    “Alkenylcopper derivatives; 21. Synthesis of allylic amides and amines by amidomethylation of alkenylcopper and -cuprate reagents”
    Synthesis 1984, 40-43.
  1. A. Alexakis, G. Cahiez, J.F. Normant,
    “Z-1-Iodohexene”
    Organic Syntheses 1984, 62, 1-8.
  1. N. Jabri, A. Alexakis, J.F. Normant,
    “Alkenyl-copper derivatives. 20. Preparation of polysubstituted conjugated dienes by coupling of alkenyl halides with alkenyl copper reagents”
    Bull. Chem. Soc. Fr. 1983, 332-338.
  1. N. Jabri, A. Alexakis, J.F. Normant,
    “Alkenyl-copper derivatives. 19. Synthesis of conjugated dienes and styrenes by coupling of alkenyl cuprates with alkenyl and aryl halides”
    Bull. Chem. Soc. Fr. 1983, 321-331.
  1. F. Scott, B.G. Mafunda, J.F. Normant, A. Alexakis,
    “Spiroannelation via gem-dihalocyclopropane substrates and a cyclocuprate species”
    Tetrahedron Lett. 1983, 24, 5767-5770.
  1. N. Jabri, A. Alexakis, J.F. Normant,
    “Alkenylcopper derivatives. 24. Stereospecific synthesis of enones by palladium-catalyzed acylation of alkenylcopper reagents”
    Tetrahedron Lett. 1983, 24, 5081-5084.
  1. A. Alexakis, A. Commercon, C. Coulentianos, J.F. Normant,
    “Carbocupration of acetylenic acetals and ketals: synthesis of α,β ethylenic acetals, and of dienals and dienones”
    Pure Appl. Chem. 1983, 55, 1759-1766.
  1. J.F. Normant, A. Alexakis,
    “Preparation of conjugated dienes and enynes via organocopper reagents”
    in Transition Metals in Organic Synthesis; R. Scheffold (Ed.)John Wiley: Salle + Sauerlander, 1983; Vol. 3; p. 139-171.
  1. M. Gardette, A. Alexakis, J.F. Normant,
    “Synthesis of (Z,Z)-3,13-octadecadien-1-yl acetate. Component of the sex pheromone of Synanthedon tenuis”
    J. Chem. Ecology 1983, 9, 225-233.
  1. M. Gardette, A. Alexakis, J.F. Normant,
    “Synthesis of (Z)-13-Hexadecen-11-yn-1-yl acetate, major component of the sex pheromone of the Processionary moth”
    J. Chem. Ecology 1983, 9, 219-223.
  1. J.F. Normant, A. Alexakis,
    “New access to conjugated dienes via carbocupration of alkynes”
    in Current Trends in Organic Synthesis; H. Nozaki (Ed.)Pergamon: Oxford, 1983; p. 291-302.
  1. P. Mangeney, A. Alexakis, J.F. Normant,
    “Synthèse asymétrique d'aldéhydes à partir d'oxazolidines chirales α,β-insaturées et d'organocuprates”
    Tetrahedron Lett. 1983, 24, 373-374.
  1. M. Gardette, A. Alexakis, J.F. Normant,
    “Organocuivreux vinyliques 17. Carbocupration d'alcynes par des organocuprates et cuivreux fonctionnels”
    Tetrahedron Lett. 1982, 23, 5155-5158.
  1. A. Alexakis, J.F. Normant,
    “Vinyl-copper reagents 16. Synthesis of conjugated dienes via the addition of vinyl cuprates to acetylene”
    Tetrahedron Lett. 1982, 23, 5151-5154.
  1. N. Jabri, A. Alexakis, J.F. Normant,
    “Vinyl-copper derivatives 15. An efficient synthesis of polysubstituted conjugated dienes”
    Tetrahedron Lett. 1982, 23, 1589-1592.
  1. A. Alexakis,
    “Réactifs organo-cuivreux : nouveaux agents de synthèse de pheromone sexuelle d'insectes”
    in Les mediateurs chimiques agissant sur le comportement des insectes; Les colloques de l'INRA, Vol. 7; , 1982; p. 33-41.
  1. J.F. Normant, A. Alexakis,
    “Carbometallation (C-Metallation) of Alkynes: Stereospecific Synthesis of Alkenyl Derivatives”
    Synthesis 1981, 841-870.
  1. N. Jabri, A. Alexakis, J.F. Normant,
    “Organo-cuivreux vinyliques 14. Arylation des cuprates vinyliques”
    Tetrahedron Lett. 1981, 22, 3851-3852.
  1. N. Jabri, A. Alexakis, J.F. Normant,
    “Vinyl-copper derivatives XIII: Synthesis of conjugated dienes of very high stereoisomeric purity”
    Tetrahedron Lett. 1981, 22, 959-962.
  1. C. Germon, A. Alexakis, J.F. Normant,
    “Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents”
    Tetrahedron Lett. 1980, 21, 3763-3766.
  1. A. Alexakis, G. Cahiez, J.F. Normant,
    “Vinylcopper derivatives. XI. Reactivity of Z-alkenylcuprates towards various electrophiles. Application to the synthesis of some natural products”
    Tetrahedron 1980, 36, 1961-1969.
  1. G. Cahiez, A. Alexakis, J.F. Normant,
    “Simple stereospecific synthesis of the insect sex pheromones of Cossus cossus, Eupoecilia ambiguella, and Orgyia pseudotsugata”
    Tetrahedron Lett. 1980, 21, 1433-1436.
  1. J.F. Normant, A. Alexakis, G. Cahiez,
    “Action d'organolithiens et organomagnésiens sur la propiolactone en présence de sels cuivreux. Synthèse d'acides carboxyliques”
    Tetrahedron Lett. 1980, 21, 935-938.
  1. A. Alexakis, G. Cahiez, J.F. Normant,
    “Vinyl-copper derivatives X. Alkylation of (Z) dialkenyl cuprates”
    Synthesis 1979, 826-830.
  1. A. Alexakis, G. Cahiez, J.F. Normant,
    “Organocuivreux vinyliques IX. Addition de dérivés organiques du cuivre sur l'acétylène”
    J. Organomet. Chem. 1979, 177, 293-298.
  1. G. Friour, A. Alexakis, G. Cahiez, J.F. Normant,
    “Réactivité des dérivés organomanganeux VI. Carbonatation”
    Bull. Soc. Chim. Fr. 1979, 515-517.
  1. G. Cahiez, A. Alexakis, J.F. Normant,
    “Organomanganese(II) reagents. V. Organomanganous chlorides as a new reagent for ketone synthesis via mixed or symmetrical anhydrides”
    Synthetic Comm. 1979, 9, 639-645.
  1. A. Alexakis, M.J. Chapdelaine, G.H. Posner,
    “A new approach to the bicyclo[3.2.1]octane ring system: Intramolecular michael and aldol reactions of 3-(5-oxohexyl)-2-cyclopentenones”
    Tetrahedron Lett. 1978, 19, 4209-4212.
  1. A. Alexakis, M.J. Chapdelaine, G.H. Posner, A.W. Runquist,
    “A new synthetic approach to Pseudoguaianes”
    Tetrahedron Lett. 1978, 19, 4205-4208.
  1. J.F. Normant, T. Mulamba, F. Scott, A. Alexakis, G. Cahiez,
    “Substitution directe de l'halogène d'halohydrines 1-2 par des organomagnésiens et lithiens en présence de sels cuivreux”
    Tetrahedron Lett. 1978, 19, 3711-3712.
  1. G. Cahiez, A. Alexakis, J.F. Normant,
    “Dérivés organomagnésiens ω-alcoolates : préparation et réactivité”
    Tetrahedron Lett. 1978, 19, 3013-3014.
  1. G. Cahiez, A. Alexakis, J.F. Normant,
    “A highly stereoselective preparation of 1,4- and 1,5 alkadienes”
    Synthesis 1978, 528-30.
  1. A. Alexakis, G. Cahiez, J.F. Normant,
    “Highly stereoselective synthesis of the insect sex pheromone of Phthorimaea operculella and of propylure”
    Tetrahedron Lett. 1978, 2027-2030.
  1. J.G. Duboudin, B. Jousseaume, A. Alexakis, G. Cahiez, J. Villieras, J.F. Normant,
    “Addition comparée d'organocuivreux, d'organocuprates et d'organomagnésiens en présence de Cu(I) en quantité catalytique sur l'alcool propargylique”
    C. R. Acad. Sc. Paris, Ser. C. 1977, 285, 29-31.
  1. G.H. Posner, C.E. Whitten, J.J. Sterling, D.J. Brunelle, C.M. Lentz, A.W. Runquist, A. Alexakis,
    “New organocopper synthetic methods. α,β-dialkylation of α,β-ethylenic ketones : synthesis of sesquiterpenes”
    Ann. New York Acad. Sci. 1977, 295, 249-253.
  1. A. Alexakis, G. Cahiez, J.F. Normant, J. Villieras,
    “Organo-cuivreux vinyliques VIII. Etude de la régio-sélectivité de l'addition des dérivés organo-cuivreux sur les alcynes hétérosubstitués. Utilisation en synthèse des complexes organo-cuivreux obtenus”
    Bull. Soc. Chim. Fr. 1977, 693-698.
  1. A. Alexakis, J. Normant, J. Villieras,
    “Dérivés organo-cuivreux vinyliques VII. Addition de l'acétylène sur des cuprates lithiens : synthèse d'homo et d'hétéro-vinyl cuprates lithiens (Z)”
    Tetrahedron Lett. 1976, 17, 3461-3462.
  1. A. Alexakis, A. Commerçon, J. Villieras, J.F. Normant,
    “Dérivés organo-cuivreux vinyliques VI. Addition régiosélective d'organocuprates sur des acétals α-acétyléniques. Synthèse d'un acétal du Géranial”
    Tetrahedron Lett. 1976, 17, 2313-2316.
  1. A. Alexakis,
    “Etude de la régiosélectivité de l'addition d'organo-cuivreux sur des alcynes fonctionnels”
    Thèse de doctorat d\'Etat Paris 1975, 23 Jan., N° CNRS : AO 12960.
  1. A. Alexakis, J.F. Normant, J. Villieras,
    “Organo-vinyl-copper compounds V. Regioselectivity in the addition of alkyl-copper-magnesium bromide reagents on various propargyl derivatives”
    J. Mol. Catal. 1975, 1, 43-58.
  1. A. Alexakis, J. Normant, J. Villieras,
    “Organocuivreux vinyliques : IV. Etude de la régiosélectivité de l'addition d'un alkyl-cuivre sur des alcynes β et γ fonctionnels”
    J. Organomet. Chem. 1975, 96, 471-485.
  1. J.F. Normant, A. Alexakis, A. Commercon, G. Cahiez, J. Villieras,
    “Organocuivreux alcoxy et alkylthio-vinyliques : intermédiaires de synthèse d'alcènes hétérosubstitués stéréospécifiquement”
    C. R. Acad. Sc. Paris, Ser. C. 1974, 279, 763-765.
  1. J.F. Normant, A. Alexakis, J. Villieras,
    “Addition d'alkyl-cuivres sur divers dérivés propargyliques”
    J. Organomet. Chem. 1973, 57, C99-C102.
  1. J.F. Normant, G. Cahiez, C. Chuit, A. Alexakis, J. Villieras,
    “Synthèse stéréospécifique d'oléfines di- et trisubstituées par alcoylation des vinyl cuivres”
    J. Organomet. Chem. 1972, 40, C49-C52.