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Publication 237
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A. Alexakis, M. Vuagnoux-d'Augustin, D. Martin, S. Kehrli,
“Formation of all-carbon chiral quaternary centers by copper catalysed asymmetric cojugate addition”
Latvija kimijas zurnals 2007, 373-377.
In summary, the copper-catalyzed asym. conjugate addn. of both organoaluminum and organomagnesium reagents affords a viable methodol. for the creation of all-carbon chiral quaternary centers. Several applications in natural product synthesis are possible, particularly when an angular Me group is needed on bicyclic systems.
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