Département de chimie organique Département de chimie organique

Publications

  1. Access to 1,2- and 1,3-Amino Alcohols via Cu-Catalyzed Enantioselective Borylations of Allylamines
    Arthur Flaget, Clément Mazet*
    Org. Lett. 2024, 26, 8542-8547
  1. Ni-Catalyzed Kumada–Corriu Cross-Coupling Reactions of Tertiary Grignard Reagents and Bromostyrenes
    Kaidi Li, Bing Zu, Clément Mazet*
    Org. Lett. 2024, 26, 6047-6052
  1. Remote Functionalization by Pd-Catalyzed Isomerization of Alkynyl Alcohols
    Simone Scaringi, Baptiste Leforestier, Clément Mazet*
    J. Am. Chem. Soc. 2024, 146, 18606-18615
  1. Access to Cyclic Borates by Cu-Catalyzed Borylation of Unactivated Vinylcyclopropanes
    Cheng Zhang, Clément Mazet*
    Org. Lett. 2024, 26, 5386-5390
  1. Cu-Catalyzed Enantioselective Protoboration of 2,3-Disubstituted 1,3-Dienes
    Sensheng Liu, Yangbin Liu, Arthur Flaget, Cheng Zhang, Clément Mazet*
    Org. Lett. 2023, 25, 6897-6901
  1. Pd-Catalyzed Regioselective Cyclopropanation of 2-Substituted 1,3-Dienes
    Agonist Kastrati, Vincent Jaquier, Michele Garbo, Céline Besnard, Clément Mazet*
    ACS Org. Inorg. Au 2023, 3, 291-298
  1. Assisted Tandem Pd Catalysis Enables Regiodivergent Heck Arylation of Transiently Generated Substituted Enol Ethers
    Thomas Duhamel, Simone Scaringi, Baptiste Leforestier, Amalia I. Poblador-Bahamonde, Clément Mazet*
    JACS Au 2023, 3, 261-274
  1. Ni-Catalyzed Enantioselective Hydrofunctionalizations of 1,3-Dienes
    Arthur Flaget, Cheng Zhang, Clément Mazet*
    ACS Catal. 2022, 12, 15638-15647
  1. Transition metal-catalyzed (remote) deconjugative isomerization of α,β-unsaturated carbonyls
    Simone Scaringi, Clément Mazet*
    Tetrahedron Lett. 2022, 96, 153756-153742
  1. Stereoselective Access to Conjugated and Cross-Conjugated Dienoates by Rh- and Ru-Catalyzed Isomerizations of Vinylcyclopropanes
    Michele Garbo, Clément Mazet*
    Org. Lett. 2022, 24, 752-756
  1. Nickel-Catalyzed Kumada Vinylation of Enol Phosphates: A Comparative Mechanistic Study
    Philippe-Alexandre Poisson, Gaël Tran, Céline Besnard, Clément Mazet*
    ACS Catal. 2021, 11, 15041-15050
  1. Teflon Magnetic Stirring Capsules (TMSC) as a Practical and Reusable Delivery System for Sensitive Reagents and Catalysts
    Sylvain Taillemaud, Stéphane Rosset, Clément Mazet*
    Helv. Chim. Acta 2021, 104, e2100110
  1. Access to Highly Stereodefined 1,4-cis-Polydienes by a [Ni/Mg] Orthogonal Tandem Catalytic Polymerization
    Daniele Fiorito, Malaury Simon, Christophe M. Thomas,* Clément Mazet*
    J. Am. Chem. Soc. 2021, 143, 13401-13407
  1. Kinetically Controlled Stereoselective Access to Branched 1,3-Dienes by Ru-Catalyzed Remote Conjugative Isomerization
    Simone Scaringi, Clément Mazet*
    ACS Catal. 2021, 11, 7970-7977
  1. Bioinspired Ether Cyclizations within a π-Basic Capsule Compared to Autocatalysis on π-Acidic Surfaces and Pnictogen-Bonding Catalysts
    Xiaoyu Hao, Tian-Ren Li, Hao Chen, Andrea Gini, Xiang Zhang, Stéphane Rosset, Clément Mazet, Konrad Tiefenbacher,* Stefan Matile*
    Chem. Eur. J. 2021, 27, 12215-12223
  1. Transition metal-catalyzed alkene isomerization as an enabling technology in tandem, sequential and domino processes
    Daniele Fiorito, Simone Scaringi, Clément Mazet*
    Chem. Soc. Rev. 2021, 50, 1391-1406
  1. Ni-Catalyzed Regiodivergent and Stereoselective Hydroalkylation of Acyclic Branched Dienes with Unstabilized C(sp3) Nucleophiles
    Wen Shao, Céline Besnard, Laure Guénée, Clément Mazet*
    J. Am. Chem. Soc. 2020, 142, 16486-16492
  1. Access to Optically Active 7-Membered Rings by a 2-Step Synthetic Sequence: Cu-Catalyzed Stereoselective Cyclopropanation of Branched 1,3-Dienes/Rh-Catalyzed Stereoconvergent [5+2] Cycloaddition
    Michele Garbo, Céline Besnard, Laure Guénée, Clément Mazet*
    ACS Catal. 2020, 10, 9604-9611
  1. [n]Dendralenes as a Platform for Selective Catalysis: Ligand-Controlled Cu-Catalyzed Chemo-, Regio-, and Enantioselective Borylations
    Camille Desfeux, Céline Besnard, Clément Mazet*
    Org. Lett. 2020, 22, 8181-8187
  1. A Catalytic Dual Isomerization/Allylboration Sequence for the Stereoselective Construction of Congested Secondary Homoallylic Alcohols
    Yangbin Liu, Clément Mazet*
    J. Org. Chem. 2020, 85, 5638-5650
  1. Direct Access to Chiral Secondary Amides by Copper-Catalyzed Borylative Carboxamidation of Vinylarenes with Isocyanates
    Daniele Fiorito, Yangbin Liu, Celine Besnard, Clément Mazet*
    J. Am. Chem. Soc. 2020, 142, 623-632
  1. Ni-Catalyzed Regioselective Hydroalkoxylation of Branched 1,3-Dienes
    Gaël Tran, Clément Mazet*
    Org. Lett. 2019, 21, 9124-9127
  1. Remote Functionalization of α,β-Unsaturated Carbonyls by Multimetallic Sequential Catalysis
    Ciro Romano, Daniele Fiorito, Clément Mazet*
    J. Am. Chem. Soc. 2019, 141, 16983-16990
  1. Ni-Catalyzed Enantioselective Intermolecular Hydroamination of Branched 1,3-Dienes Using Primary Aliphatic Amines
    Gaël Tran, Wen Shao, Clément Mazet*
    J. Am. Chem. Soc. 2019, 141, 14814-14822
  1. Editorial: Organometallics and Catalysis
    Clément Mazet*
    CHIMIA 2018, 72, 577
  1. Ir-Catalyzed Selective Hydroboration of 2-Substituted 1,3-Dienes: A General Method to Access Homoallylic Boronates
    Daniele Fiorito, Clément Mazet*
    ACS Catal. 2018, 8, 9382-9387
  1. Copper-Catalyzed Enantioselective 1,2-Borylation of 1,3-Dienes
    Yangbin Liu, Daniele Fiorito, Clément Mazet*
    Chem. Sci. 2018, 9, 5284-5288
  1. Multicatalytic Stereoselective Synthesis of Highly Substituted Alkenes by Sequential Isomerization/Cross-Coupling Reactions
    Ciro Romano, Clément Mazet*
    J. Am. Chem. Soc. 2018, 140, 4743-4750
  1. A General Nickel-Catalyzed Kumada Vinylation for the Preparation of 2-Substituted 1,3-Dienes
    Daniele Fiorito, Sarah Folliet, Yangbin Liu, Clément Mazet*
    ACS Catal. 2018, 8, 1392-1398
  1. Mechanistic Investigation of the Pd-Catalyzed Intermolecular Carboetherification and Carboamination of 2,3-Dihydrofuran: Similarities, Differences, and Evidence for Unusual Reaction Intermediates
    Gustavo M. Borrajo-Calleja, Vincent Bizet, Céline Besnard, Clément Mazet*
    Organometallics 2017, 36, 3553-3563
  1. Exploring Site Selectivity of Iridium Hydride Insertion into Allylic Alcohols: Serendipitous Discovery and Comparative Study of an Organic and an Organometallic Catalysts for the Vinylogous Peterson Elimination
    Houhua Li, Daniele Fiorito, Clément Mazet*
    ACS Catal. 2017, 7, 1554-1562
  1. Influence of the Dissolution Solvent on the Cytotoxicity of Octahedral Cationic Ir(III) Hydride Complexes
    Huaiyi Huang, Nicolas Humbert, Vincent Bizet, Malay Patra, Hui Chao,* Clément Mazet,* Gilles Gasser*
    J. Organomet. Chem. 2017, 839, 15-18
  1. Magnetic Stirring Capsules
    Stéphane Rosset, Clément Mazet, Christophe Girard
    International Patent Application 2017, WO/2017/216361
  1. Direct Access to Furoindolines by Palladium-Catalyzed Intermolecular Carboamination
    Vincent Bizet, Gustavo M. Borrajo-Calleja, Celine Besnard, Clément Mazet*
    ACS Catal. 2016, 6, 7183-7187
  1. The Diastereoselective Synthesis of Octahedral Cationic Iridium Hydride Complexes with a Stereogenic Metal Centre
    Nicolas Humbert, Clément Mazet*
    Chem. Commun. 2016, 52, 10629-10631
  1. Palladium-Catalyzed Long-Range Deconjugative Isomerization of Highly Substituted α,β-Unsaturated Carbonyl Compounds
    Luqing Lin, Ciro Romano, Clément Mazet*
    J. Am. Chem. Soc. 2016, 138, 10344-10350
  1. Iridium-Catalyzed Selective Isomerization of Primary Allylic Alcohols
    Houhua Li, Clément Mazet*
    Acc. Chem. Res. 2016, 49, 1232-1241
  1. Palladium-Catalyzed Enantioselective Intermolecular Carboetherification of Dihydrofurans
    Gustavo M. Borrajo Calleja, Vincent Bizet, Clément Mazet*
    J. Am. Chem. Soc. 2016, 138, 4014-4017
  1. Organometallic Complexes of Iridium (Update 2015)
    Houhua Li, Clément Mazet*
    in SOS Science of Synthesis; R. Alan Aitken, Mogens Brønsted Nielsen, Jozef Drabowicz, Jie Jack Li, Bernd J. Plietker, Thomas Wirth (Eds.)Thieme: Stuttgart - New York, 2016; Knowledge Updates 2015/2; p. 21-58
  1. Pd2Au36(SR)24 cluster: structure studies
    Bei Zhang, Sameh Kaziz, Houhua Li, Dawid Wodka, Sami Malola, Olga V. Safonova, Maarten Nachtegaal, Clément Mazet, Igor Dolamic, Jordi Llorca, Elina Kalenius, Latévi Max Lawson Daku, Hannu Häkkinen, Thomas Bürgi,* Noelia Barrabés*
    Nanoscale 2015, 7, 17012-17019
  1. Catalyst-Directed Diastereoselective Isomerization of Allylic Alcohols for the Stereoselective Construction of C(20) in Steroid Side Chains: Scope and Topological Diversification
    Houhua Li, Clément Mazet*
    J. Am. Chem. Soc. 2015, 137, 10720-10727
  1. Access to Enantioenriched 2,3- and 2,5-Dihydrofurans with a Fully Substituted C2 Stereocenter by Pd-Catalyzed Asymmetric Intermolecular Heck Reaction
    Gustavo M. Borrajo Calleja, Vincent Bizet, Thomas Bürgi, Clément Mazet*
    Chem. Sci. 2015, 6, 4807-4811
  1. A general Pd-catalyzed α− and γ−benzylation of aldehydes for the formation of quaternary centers
    Ivan Franzoni, Laure Guénée, Clément Mazet*
    Org. Biomol. Chem. 2015, 13, 6338-6343
  1. Modulation of Active Sites in Supported Au38(SC2H4Ph)24 Cluster Catalysts: Effect of Atmosphere and Support Material
    Bei Zhang, Sameh Kaziz, Houhua Li, Miguel González Hevia, Dawid Wodka, Clément Mazet, Thomas Bürgi,* Noelia Barrabés*
    J. Phys. Chem. C 2015, 119, 11193-11199
  1. Scope and Mechanism in Palladium-Catalyzed Isomerizations of Highly Substituted Allylic, Homoallylic and Alkenyl Alcohols
    Evgeny Larionov, Luqing Lin, Laure Guénée, Clément Mazet*
    J. Am. Chem. Soc. 2014, 136, 16882-16894
  1. An Air-stable Cationic Iridium Hydride as a Highly Active and General Catalyst for the Isomerization of Terminal Epoxides
    Nicolas Humbert, Devendra J. Vyas, Céline Besnard, Clément Mazet*
    Chem. Commun. 2014, 50, 10592-10595
  1. Well-defined Transition Metal Hydrides in Catalytic Isomerizations
    Evgeny Larionov, Houhua Li, Clément Mazet*
    Chem. Commun. 2014, 50, 9816-9826
  1. Chiral Monodentate Phosphine Ligands for the Enantioselective α− and γ−arylation of Aldehydes
    Ivan Franzoni, Laure Guénée, Clément Mazet*
    Tetrahedron 2014, 70, 4181-4190
  1. Highly Modular C1-Symmetric Chiral (P,N) Ligands with a Stereolabile P Center: Experimental and Theoretical Studies
    Nicolas Humbert, Evgeny Larionov, Luca Mantilli, Pradeep Nareddy, Céline Besnard, Laure Guénée, Clément Mazet*
    Chem. Eur. J. 2014, 20, 745-751
  1. Recent Trends in Pd-catalyzed Remote Functionalization of Carbonyl Compounds
    Ivan Franzoni, Clément Mazet*
    Org. Biomol. Chem. 2014, 12, 233-241
  1. Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols
    Houhua Li, Clément Mazet*
    Org. Lett. 2013, 15, 6170-6173
  1. Complementary Catalytic Strategies to Access α-Chiral Aldehydes
    Clément Mazet*
    CHIMIA 2013, 67, 658-662
  1. α-Arylation, α-Arylative Esterification, or Acylation: A Stoichiometry-Dependent Trichotomy in the Pd-Catalyzed Cross-Coupling between Aldehydes and Aryl Bromides
    Pradeep Nareddy, Clément Mazet*
    Chem. Asian J. 2013, 8, 2579-2583
  1. Access to Congested Quaternary Centers by Pd-catalyzed Intermolecular γ-arylation of Unactivated α,β-unsaturated Aldehydes
    Ivan Franzoni, Laure Guénée, Clément Mazet*
    Chem. Sci. 2013, 4, 2619-2624
  1. Isomerization of Terminal Epoxides by a [Pd-H] Catalyst: A Combined Experimental and Theoretical Mechanistic Study
    Devendra J. Vyas, Evgeny Larionov, Céline Besnard, Laure Guénée, Clément Mazet*
    J. Am. Chem. Soc. 2013, 135, 6177-6183
  1. Challenges and Achievements in the Transition Metal-catalyzed Asymmetric α-Arylation of Aldehydes
    Clément Mazet*
    Synlett 2012, 23, 1999-2004
  1. Structure-Activity Relationship in the Iridium-Catalyzed Isomerization of Primary Allylic Alcohols
    Luca Mantilli, David Gérard, Céline Besnard, Clément Mazet*
    Eur. J. Inorg. Chem. 2012, 20, 3320-3330
  1. Atropoisomeric (P,N) Ligands for the Highly Enantioselective Pd-Catalyzed Intramolecular Asymmetric α-Arylation of α-Branched Aldehydes
    Pradeep Nareddy, Luca Mantilli, Laure Guénée, Clément Mazet*
    Angew. Chem. Int. Ed. 2012, 51, 3826-3831
  1. Privileged Chiral Ligands and Catalysts (book review)
    Clément Mazet*
    Angew. Chem. Int. Ed. 2012, 51, 305
  1. New Catalytic Asymmetric Strategies to Access Chiral Aldehydes
    Clément Mazet*
    CHIMIA 2011, 65, 802-805
  1. Platinum Metals in the Asymmetric Isomerization of Allylic Alcohols
    Luca Mantilli, Clément Mazet*
    Chem. Lett. 2011, 40, 341-344
  1. Access to High Levels of Molecular Complexity by One-Pot Iridium/Enamine Asymmetric Catalysis
    Adrien Quintard, Alexandre Alexakis,* Clément Mazet*
    Angew. Chem. Int. Ed. 2011, 50, 2354-2358
  1. Highly Regio- and Enantioselective Catalytic Asymmetric Hydroboration of α-Substituted Styrenyl Derivatives
    Clément Mazet,* David Gérard
    Chem. Commun. 2011, 47, 298-300
  1. Improved Catalysts for the Iridium-catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Based on Charton Analysis
    Luca Mantilli, David Gérard, Sonya Torche, Céline Besnard, Clément Mazet*
    Chem. Eur. J. 2010, 16, 12736-12745
  1. The 3rd Young Faculty Meeting – Looking Back at the Past to Better Anticipate the Future
    Barbara Winter-Werner,* Clément Mazet*
    CHIMIA 2010, 64, 621-622
  1. The 45th EUCHEM Conference on Stereochemistry (Bürgenstock Conference 2010)
    Clément Mazet,* Cristina Nevado*
    CHIMIA 2010, 64, 421-424
  1. Highly Enantioselective Isomerization of Primary Allylic Alcohols Catalyzed by (P,N)-iridium complexes
    Luca Mantilli, David Gérard, Sonya Torche, Céline Besnard, Clément Mazet*
    Pure Appl. Chem. 2010, 82, 1461-1469
  1. Copper-Catalyzed Asymmetric β-Boration of α,β-Unsaturated Carbonyl Derivatives
    Luca Mantilli, Clément Mazet*
    ChemCatChem 2010, 2, 501-504
  1. Expanded Scope for the Iridium-catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Using Readily Accessible Second-generation Catalysts
    Luca Mantilli, Clément Mazet*
    Chem. Commun. 2010, 46, 445-447
  1. Organic Chemistry à la Genevoise
    Clément Mazet, Andreas Zumbuehl, Damien Jeannerat, Jiri Mareda, Alexandre Alexakis, E. Peter Kündig, Jérôme Lacour, Stefan Matile
    CHIMIA 2009, 63, 816-821
  1. Iridium-catalyzed Asymmetric Isomerization of Primary Allylic Alcohols
    Luca Mantilli, David Gérard, Sonya Torche, Céline Besnard, Clément Mazet*
    Angew. Chem. Int. Ed. 2009, 48, 5143-5147
  1. Iridium-catalyzed Isomerization of Primary Allylic Alcohols Under Mild Reaction Conditions
    Luca Mantilli, Clément Mazet*
    Tetrahedron Lett. 2009, 50, 4141-4144
  1. Iridium-catalyzed Isomerization of Primary Allylic Alcohols
    Luca Mantilli, Clément Mazet*
    CHIMIA 2009, 63, 35-37
  1. Chiral Boron-Bridged Bisoxazoline (Borabox) Ligands: Structures and Reactivities of Pd and Cu Complexes
    Valentin Köhler, Clément Mazet, Aurélie Toussaint, Klaus Kulicke, Daniel Häussinger, Markus Neuburger, Silvia Schaffner, Stefan Kaiser, Andreas Pfaltz*
    Chem. Eur. J. 2008, 14, 8530-8539
  1. Dinuclear {(salen)Al} Complexes Display Expanded Scope in the Conjugate Cyanation of α,β-Unsaturated Imides
    Clément Mazet, Eric N. Jacobsen*
    Angew. Chem. Int. Ed. 2008, 47, 1762-1765
  1. Kinetic Resolution of Diols and Pyridyl Alcohols by Cu(II)(borabox)-Catalyzed Acylation
    Clément Mazet, Stephen Roseblade, Valentin Köhler, Andreas Pfaltz*
    Org. Lett. 2006, 8, 1879-1882
  1. Synthesis of Chiral Boron-bridged Anionic C2-symmetric Bisoxazolines and their Applications in Asymmetric Catalysis
    Clément Mazet,* Valentin Köhler, Stephen Roseblade, Aurélie Toussaint, Andreas Pfaltz*
    CHIMIA 2006, 60, 195-198
  1. Chiral Boron-Bridged Bisoxazolines: Readily Available Anionic Ligands for Asymmetric Catalysis
    Clément Mazet, Valentin Köhler, Andreas Pfaltz*
    Angew. Chem. Int. Ed. 2005, 44, 4888-4891
  1. A Combined Experimental and Computational Study of Dihydrido-Phosphinooxazoline Iridium Complexes
    Clément Mazet, Sebastian P. Smidt, Markus Meuwly,* Andreas Pfaltz*
    J. Am. Chem. Soc. 2004, 126, 14176-14181
  1. Synthesis and Coordination Chemistry of the First C2-Chiral Bisoxazine Ligand
    Clément Mazet, Lutz H. Gade*
    Inorg. Chem. 2003, 42, 210-215
  1. [Bis(oxazolinyl)pyrrole]palladium Complexes as Catalysts in Heck- and Suzuki-Type C-C Coupling Reactions
    Clément Mazet, Lutz H. Gade*
    Eur. J. Inorg. Chem. 2003, 1161-1168
  1. Double Bonds in Motion: Bis(oxazolinylmethyl)pyrroles and Their Metal-Induced Planarization to a New Class of Rigid Chiral C2-symmetric Complexes
    Clément Mazet, Lutz H. Gade*
    Chem. Eur. J. 2003, 9, 1759-1767
  1. Charging and Deforming the Pybox Ligand: Enantiomerically Pure Double Helices and Their Interconversion
    Clément Mazet, Lutz H. Gade*
    Chem. Eur. J. 2002, 8, 4308-4318
  1. Solution Structure and Decomposition Pathway of Zwitterionic Zirconium(IV) Benzyl Complexes
    Régis M. Gauvin, Clément Mazet, Jacky Kress*
    J. Organomet. Chem. 2002, 658, 1-8
  1. A Bis(oxazolinyl)pyrrole as a New Monoanionic Tridentate Supporting Ligand: Synthesis of a Highly Active Palladium Catalyst for Suzuki-Type C-C Coupling
    Clément Mazet, Lutz H. Gade*
    Organometallics 2001, 20, 4144-4146